BINOL Modification via SNAr Reactions with Pentafluoropyridine

Koltunov, Konstantin Yurievich; Chernov, Aleksey Nikolaevich

doi:10.1016/j.mencom.2015.01.014

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BINOL Modification via S_NAr Reactions with Pentafluoropyridine

Konstantin Yurievich Koltunov ^{1, 2}

Konstantin Yurievich Koltunov

,

Aleksey Nikolaevich Chernov ^{2, 3}

Aleksey Nikolaevich Chernov

¹ G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

² Department of Natural Sciences, Novosibirsk State University, Novosibirsk, Russian Federation

³ V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

10.1016/j.mencom.2015.01.014

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Published 2014-12-26

Communication , Volume 25, Issue 1, 39-40

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Koltunov K. Y., Chernov A. N. BINOL Modification via SNAr Reactions with Pentafluoropyridine // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 39-40.

GOST all authors (up to 50) Copy

Koltunov K. Y., Chernov A. N. BINOL Modification via SNAr Reactions with Pentafluoropyridine // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 39-40.

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TY - JOUR

DO - 10.1016/j.mencom.2015.01.014

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.014

TI - BINOL Modification via SNAr Reactions with Pentafluoropyridine

T2 - Mendeleev Communications

AU - Koltunov, Konstantin Yurievich

AU - Chernov, Aleksey Nikolaevich

PY - 2014

DA - 2014/12/26

PB - Mendeleev Communications

SP - 39-40

IS - 1

VL - 25

ER -

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@article{2014_Koltunov,

author = {Konstantin Yurievich Koltunov and Aleksey Nikolaevich Chernov},

title = {BINOL Modification via SNAr Reactions with Pentafluoropyridine},

journal = {Mendeleev Communications},

year = {2014},

volume = {25},

publisher = {Mendeleev Communications},

month = {Dec},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.014},

number = {1},

pages = {39--40},

doi = {10.1016/j.mencom.2015.01.014}

}

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Koltunov, Konstantin Yurievich, and Aleksey Nikolaevich Chernov. “BINOL Modification via SNAr Reactions with Pentafluoropyridine.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 39-40. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.014.

Abstract

(R)- and (S)-binaphthyl-2,2’-diols (BINOLs) smoothly react with pentafluoropyridine without racemization to give (R)- and (S)-2,2’- bis(tetrafluoropyridin-4-yloxy)-1,1’-binaphthyls. The 2(6)-positioned pyridine fluorine atoms can be replaced with amino moieties by reactions with amines.

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