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Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+

, 
Nikita Vyacheslavovich Shvydkiy 1
Nikita Vyacheslavovich Shvydkiy
,  , 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
10.1016/j.mencom.2015.01.010
Published 2014-12-26
Communication , Volume 25, Issue 1, 29-31
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Perekalin D. S. et al. Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+ // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 29-31.
GOST all authors (up to 50) Copy
Perekalin D. S., Shvydkiy N. V., Nelyubina Y. V., Kudinov A. R. Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+ // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 29-31.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.010
TI - Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+
T2 - Mendeleev Communications
AU - Perekalin, Dmitrii Sergeevich
AU - Shvydkiy, Nikita Vyacheslavovich
AU - Nelyubina, Yulia Vladimirovna
AU - Kudinov, Alexander Rudolfovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 29-31
IS - 1
VL - 25
ER -
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@article{2014_Perekalin,
author = {Dmitrii Sergeevich Perekalin and Nikita Vyacheslavovich Shvydkiy and Yulia Vladimirovna Nelyubina and Alexander Rudolfovich Kudinov},
title = {Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.010},
number = {1},
pages = {29--31},
doi = {10.1016/j.mencom.2015.01.010}
}
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Perekalin, Dmitrii Sergeevich, et al. “Synthesis of the half-sandwich ruthenium complexes [Cp*RuL3]+ via naphthalene replacement in [Cp*Ru(C10H8)]+.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 29-31. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.010.

Abstract

The cation [Cp*Ru(C10H8)]+ exchanges naphthalene for various ligands under near-UV (365nm) or visible light irradiation giving the half-sandwich complexes [Cp*RuL3]+ [L = P(OMe)3, 1,3,5-triaza-7-phosphaadamantane, ButNC], [Cp*Ru(dppe)(MeCN)]+, Cp*Ru(CO)2Cl, Cp*Ru[tris(pyrazolyl)borate] and [Cp*Ru(C6H6)]+ in 80–95% yields.

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