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First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study

Dmitry Grigorievich Yakhvarov 1, 2
Dmitry Grigorievich Yakhvarov
, 
Ekaterina Alexandrovna Trofimova 1
Ekaterina Alexandrovna Trofimova
, 
Alexey Borisovich Dobrynin 1
Alexey Borisovich Dobrynin
, 
Tatiana Pavlovna Gerasimova 1
Tatiana Pavlovna Gerasimova
, 
Sergey Alexandrovich Katsyuba 1
Sergey Alexandrovich Katsyuba
, 
10.1016/j.mencom.2015.01.009
Published 2014-12-26
Communication , Volume 25, Issue 1, 27-28
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Yakhvarov D. G. et al. First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 27-28.
GOST all authors (up to 50) Copy
Yakhvarov D. G., Trofimova E. A., Dobrynin A. B., Gerasimova T. P., Katsyuba S. A., Sinyashin O. G. First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 27-28.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.009
TI - First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study
T2 - Mendeleev Communications
AU - Yakhvarov, Dmitry Grigorievich
AU - Trofimova, Ekaterina Alexandrovna
AU - Dobrynin, Alexey Borisovich
AU - Gerasimova, Tatiana Pavlovna
AU - Katsyuba, Sergey Alexandrovich
AU - Sinyashin, Oleg Gerol'dovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 27-28
IS - 1
VL - 25
ER -
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@article{2014_Yakhvarov,
author = {Dmitry Grigorievich Yakhvarov and Ekaterina Alexandrovna Trofimova and Alexey Borisovich Dobrynin and Tatiana Pavlovna Gerasimova and Sergey Alexandrovich Katsyuba and Oleg Gerol'dovich Sinyashin},
title = {First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.009},
number = {1},
pages = {27--28},
doi = {10.1016/j.mencom.2015.01.009}
}
MLA
Cite this
MLA Copy
Yakhvarov, Dmitry Grigorievich, et al. “First neutral dinuclear cobalt complex formed by bridging [μ-O2P(H)R]– ligands: synthesis, X-ray crystal structure and quantum-chemical study.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 27-28. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.009.

Abstract

The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and 9-anthrylphosphinic acid AntP(O)(OH)H (Ant = 9-anthryl) leads to the first example of a neutral dinuclear cobalt(ii) complex {Co2Br2[μ-O2P(H)Ant]2(bpy)2} formed by two bridging [μ-O2P(H)Ant]– ligands. The complex has been characterized by X-ray diffraction analysis and quantum-chemical calculations.

References

1.
Introduction to metal-organic frameworks.
Zhou H., Long J.R., Yaghi O.M.
Chemical Reviews, 2012
4.
Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
Zhang J., Zhang Y., Lin J., Chen X.
Chemical Reviews, 2011
5.
Thermal stability of coordination polymers
Tomic E.A.
Journal of Applied Polymer Science, 1965
8.
Carbon Dioxide Capture in Metal–Organic Frameworks
Sumida K., Rogow D.L., Mason J.A., McDonald T.M., Bloch E.D., Herm Z.R., Bae T., Long J.R.
Chemical Reviews, 2011
9.
Hydrogen Storage in Metal–Organic Frameworks
Suh M.P., Park H.J., Prasad T.K., Lim D.
Chemical Reviews, 2011
11.
Metal–Organic Frameworks for Separations
Li J., Sculley J., Zhou H.
Chemical Reviews, 2011
13.
Luminescent Functional Metal–Organic Frameworks
Cui Y., Yue Y., Qian G., Chen B.
Chemical Reviews, 2011
15.
Highly Interpenetrated Metal-Organic Frameworks for Hydrogen Storage
Kesanli B., Cui Y., Smith M.R., Bittner E.W., Bockrath B.C., Lin W.
Angewandte Chemie - International Edition, 2005
16.
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Eddaoudi M., Kim J., Rosi N., Vodak D., Wachter J., O'Keeffe M., Yaghi O.M.
Science, 2002
17.
Hydrogen Storage in Microporous Metal-Organic Frameworks
Rosi N.L., Eckert J., Eddaoudi M., Vodak D.T., Kim J., O'Keeffe M., Yaghi O.M.
Science, 2003
19.
A homochiral metal–organic porous material for enantioselective separation and catalysis
Seo J.S., Whang D., Lee H., Jun S.I., Oh J., Jeon Y.J., Kim K.
Nature, 2000
20.
ℝPM-1: A Recyclable Nanoporous Material Suitable for Ship-In-Bottle Synthesis and Large Hydrocarbon Sorption
Pan L., Liu H., Lei X., Huang X., Olson D.H., Turro N.J., Li J.
Angewandte Chemie - International Edition, 2003
22.
A Homochiral Porous Metal−Organic Framework for Highly Enantioselective Heterogeneous Asymmetric Catalysis
Wu C., Hu A., Zhang L., Lin W.
Journal of the American Chemical Society, 2005
24.
A Microporous Metal–Organic Framework for Gas-Chromatographic Separation of Alkanes
Chen B., Liang C., Yang J., Contreras D.S., Clancy Y.L., Lobkovsky E.B., Yaghi O.M., Dai S.
Angewandte Chemie - International Edition, 2006
26.
Metal–Organic Framework Materials as Chemical Sensors
Kreno L.E., Leong K., Farha O.K., Allendorf M., Van Duyne R.P., Hupp J.T.
Chemical Reviews, 2011
27.
Ferroelectric metal-organic frameworks.
Zhang W., Xiong R.
Chemical Reviews, 2011
28.
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
Yoon M., Srirambalaji R., Kim K.
Chemical Reviews, 2011
30.
Metal–Organic Frameworks in Biomedicine
Horcajada P., Gref R., Baati T., Allan P.K., Maurin G., Couvreur P., Férey G., Morris R.E., Serre C.
Chemical Reviews, 2011
31.
Binuclear Metallohydrolases.
Wilcox D.E.
Chemical Reviews, 1996
34.
Biosynthesis of the thiazole moiety of thiamin pyrophosphate (vitamin B1).
Park J., Dorrestein P.C., Zhai H., Kinsland C., McLafferty F.W., Begley T.P.
Biochemistry, 2003
35.
10.1016/j.mencom.2015.01.009_sbref0060a
Adams
The Biochemistry of Nucleic Acids, 1986
36.
10.1016/j.mencom.2015.01.009_sbref0060b
Blackburn
Nucleic Acids in Chemistry and Biology, 1996
37.
10.1016/j.mencom.2015.01.009_sbref0060c
Berg
Biochemistry, 2001
38.
Kinetics of metal-catalyzed adenosine triphosphate dephosphorylation
Spiro T.G., Kjellstrom W.A., Zeydel M., Butow R.A.
Biochemistry, 1968
41.
Synthesis and Characterization of a Novel Cyclic Aluminophosphinate:  Structure and Solid-State NMR Study
Azaïs T., Bonhomme-Coury L., Vaissermann J., Bertani P., Hirschinger J., Maquet J., Bonhomme C.
Inorganic Chemistry, 2002
42.
Structural Diversity in Zinc Phosphates and Phosphinates: Observation of a Lattice Water Dimer Sandwiched Between Phosphoryl Oxygen Atoms
Pothiraja R., Shanmugan S., Walawalkar M.G., Nethaji M., Butcher R.J., Murugavel R.
European Journal of Inorganic Chemistry, 2008
43.
New dinuclear nickel(II) complexes: synthesis, structure, electrochemical, and magnetic properties.
Yakhvarov D., Trofimova E., Sinyashin O., Kataeva O., Budnikova Y., Lönnecke P., Hey-Hawkins E., Petr A., Krupskaya Y., Kataev V., Klingeler R., Büchner B.
Inorganic Chemistry, 2011
44.
Trofimova E.A., Dobrynin A.B., Gerasimova T.P., Katsyuba S.A., Sinyashin O.G., Yakhvarov D.G.
Mendeleev Communications, 2013
45.
Engineering a Metal–Organic Framework Catalyst by Using Postsynthetic Modification
Tanabe K., Cohen S.
Angewandte Chemie - International Edition, 2009
46.
Covalent radii revisited
Cordero B., Gómez V., Platero-Prats A.E., Revés M., Echeverría J., Cremades E., Barragán F., Alvarez S.
Dalton Transactions, 2008