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Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field

Galina Anatol'evna Dushenko 1, 2
Galina Anatol'evna Dushenko
, 
Igor Evguen'evich Mikhailov 1, 3
Igor Evguen'evich Mikhailov
, 
Olga Igorevna Mikhailova 1
Olga Igorevna Mikhailova
, 
Ruslan Mikhailovich Minyaev 2
Ruslan Mikhailovich Minyaev
, 
Vladimir Isaakovich Minkin 1, 2
Vladimir Isaakovich Minkin
10.1016/j.mencom.2015.01.007
Published 2014-12-26
Communication , Volume 25, Issue 1, 21-23
11
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Dushenko G. A. et al. Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 21-23.
GOST all authors (up to 50) Copy
Dushenko G. A., Mikhailov I. E., Mikhailova O. I., Minyaev R. M., Minkin V. I. Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 21-23.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.007
TI - Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field
T2 - Mendeleev Communications
AU - Dushenko, Galina Anatol'evna
AU - Mikhailov, Igor Evguen'evich
AU - Mikhailova, Olga Igorevna
AU - Minyaev, Ruslan Mikhailovich
AU - Minkin, Vladimir Isaakovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 21-23
IS - 1
VL - 25
ER -
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@article{2014_Dushenko,
author = {Galina Anatol'evna Dushenko and Igor Evguen'evich Mikhailov and Olga Igorevna Mikhailova and Ruslan Mikhailovich Minyaev and Vladimir Isaakovich Minkin},
title = {Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.007},
number = {1},
pages = {21--23},
doi = {10.1016/j.mencom.2015.01.007}
}
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Dushenko, Galina Anatol'evna, et al. “Unidirectional migration of the iodine atom over a cyclopentadiene ring in a rotating electric field.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 21-23. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.007.

Abstract

The DFT, B3LYP/Gen and 6-311++G(d,p)/SDD calculations of the reaction paths of a circumambulatory rearrangement of 5-iodocyclopentadiene showed that, under the application of a rotating electric field, the molecule behaves as a rotor-type molecular motor with the unidirectional motion of the iodine atom along the perimeter of the five-membered ring (k298 = 630 s–1).

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