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Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone

, 
Olga Olegovna Sokolova 2
Olga Olegovna Sokolova
, 
Ruslan Fedorovich Nasybullin 1
Ruslan Fedorovich Nasybullin
, 
Tatiana Aleksandrovna Zaimovskaya 3
Tatiana Aleksandrovna Zaimovskaya
, 
Mikhail Petrovich Egorov 1
Mikhail Petrovich Egorov
10.1016/j.mencom.2015.01.006
Published 2014-12-26
Communication , Volume 25, Issue 1, 19-20
7
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Elinson M. N. et al. Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 19-20.
GOST all authors (up to 50) Copy
Elinson M. N., Sokolova O. O., Nasybullin R. F., Zaimovskaya T. A., Egorov M. P. Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 19-20.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.006
TI - Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone
T2 - Mendeleev Communications
AU - Elinson, Michail Nikolaevich
AU - Sokolova, Olga Olegovna
AU - Nasybullin, Ruslan Fedorovich
AU - Zaimovskaya, Tatiana Aleksandrovna
AU - Egorov, Mikhail Petrovich
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 19-20
IS - 1
VL - 25
ER -
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@article{2014_Elinson,
author = {Michail Nikolaevich Elinson and Olga Olegovna Sokolova and Ruslan Fedorovich Nasybullin and Tatiana Aleksandrovna Zaimovskaya and Mikhail Petrovich Egorov},
title = {Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.006},
number = {1},
pages = {19--20},
doi = {10.1016/j.mencom.2015.01.006}
}
MLA
Cite this
MLA Copy
Elinson, Michail Nikolaevich, et al. “Efficient non-catalytic synthesis of substituted 2,3,4,9-tetrahydro-1H-xanthen-1-ones from salicylaldehydes and dimedone.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 19-20. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.006.

Abstract

Thermally induced non-catalytic assembling of salicylaldehydes and dimedone in water or ethanol affords 9-(2-hydroxy-4,4-dimethyl-6-oxo-1-cyclohexen-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-ones in 85–95% yields as a sequence of Knoevenagel and Michael reactions.

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