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Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Ivan A. Bidusenko 1
Ivan A. Bidusenko
, 
Natalia Aleksandrovna Cherimichkina 1
Natalia Aleksandrovna Cherimichkina
10.1016/j.mencom.2015.01.005
Published 2014-12-26
Communication , Volume 25, Issue 1, 17-18
4
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Trofimov B. A. et al. Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 17-18.
GOST all authors (up to 50) Copy
Trofimov B. A., Schmidt E. Y., Bidusenko I. A., Cherimichkina N. A. Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension // Mendeleev Communications. 2014. Vol. 25. No. 1. pp. 17-18.
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TY - JOUR
DO - 10.1016/j.mencom.2015.01.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.005
TI - Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Schmidt, Elena Yur'evna
AU - Bidusenko, Ivan A.
AU - Cherimichkina, Natalia Aleksandrovna
PY - 2014
DA - 2014/12/26
PB - Mendeleev Communications
SP - 17-18
IS - 1
VL - 25
ER -
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@article{2014_Trofimov,
author = {Boris Aleksandrovich Trofimov and Elena Yur'evna Schmidt and Ivan A. Bidusenko and Natalia Aleksandrovna Cherimichkina},
title = {Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension},
journal = {Mendeleev Communications},
year = {2014},
volume = {25},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.005},
number = {1},
pages = {17--18},
doi = {10.1016/j.mencom.2015.01.005}
}
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Trofimov, Boris Aleksandrovich, et al. “Domino assembly of functionalized cyclopentenols from 1,5-diphenylpentane-1,5-dione and phenylacetylene in the KOH/DMSO suspension.” Mendeleev Communications, vol. 25, no. 1, Dec. 2014, pp. 17-18. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2015.01.005.

Abstract

1,5-Diphenylpentane-1,5-dione reacts (50 mol% KOH in DMSO, 70°C, 3h) with phenylacetylene in a domino manner to afford 3-benzoyl-2-benzyl-1-phenylcyclopenten-1-ol and its debenzoylated derivative in 66 and 25% yields, respectively.

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