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ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide

Andrey Andreevich Mikhaylov 1
Andrey Andreevich Mikhaylov
, 
Yuliya Anatol'evna Khomutova 1
Yuliya Anatol'evna Khomutova
, 
Dmitry Evgen'evich Arkhipov 2
Dmitry Evgen'evich Arkhipov
, 
Alexander Aleksandrovich Korlyukov 2
Alexander Aleksandrovich Korlyukov
, 
Sema Leibovich Ioffe 1
Sema Leibovich Ioffe
10.1016/j.mencom.2014.11.023
Published 2014-10-30
Communication , Volume 24, Issue 6, 374-376
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Mikhaylov A. A. et al. ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 374-376.
GOST all authors (up to 50) Copy
Mikhaylov A. A., Khomutova Y. A., Arkhipov D. E., Korlyukov A. A., Ioffe S. L. ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 374-376.
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TY - JOUR
DO - 10.1016/j.mencom.2014.11.023
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.023
TI - ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide
T2 - Mendeleev Communications
AU - Mikhaylov, Andrey Andreevich
AU - Khomutova, Yuliya Anatol'evna
AU - Arkhipov, Dmitry Evgen'evich
AU - Korlyukov, Alexander Aleksandrovich
AU - Ioffe, Sema Leibovich
PY - 2014
DA - 2014/10/30
PB - Mendeleev Communications
SP - 374-376
IS - 6
VL - 24
ER -
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@article{2014_Mikhaylov,
author = {Andrey Andreevich Mikhaylov and Yuliya Anatol'evna Khomutova and Dmitry Evgen'evich Arkhipov and Alexander Aleksandrovich Korlyukov and Sema Leibovich Ioffe},
title = {ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.023},
number = {6},
pages = {374--376},
doi = {10.1016/j.mencom.2014.11.023}
}
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Cite this
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Mikhaylov, Andrey Andreevich, et al. “ButMe2SiOTf-promoted cyanosilylation of six-membered cyclic nitronates with trialkylsilyl cyanides or tert-butyl isocyanide.” Mendeleev Communications, vol. 24, no. 6, Oct. 2014, pp. 374-376. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.023.

Abstract

Six-membered cyclic nitronates smoothly react with trialkylsilyl cyanide/ButMe2SiOTf or tert-butyl isocyanide/ButMe2SiOTf systems to afford 2-trialkylsilyloxy-3-cyanotetrahydro-[4H]-1,2-oxazines or δ-oxo-α-trialkylsilyloximinonitriles depending on the ring-sub- stitution pattern.

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