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Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile

Vladimir Alekseevich Kokorekin 1
Vladimir Alekseevich Kokorekin
, 
Vitaly Vasil'evich Yanilkin 2
Vitaly Vasil'evich Yanilkin
, 
Vladimir Ivanovich Morozov 2
Vladimir Ivanovich Morozov
,  , 
Dmitry Nikolaevich Platonov 1
Dmitry Nikolaevich Platonov
, 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2014.11.018
Published 2014-10-30
Communication , Volume 24, Issue 6, 363-364
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Kokorekin V. A. et al. Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 363-364.
GOST all authors (up to 50) Copy
Kokorekin V. A., Yanilkin V. V., Morozov V. I., Tomilov Y. V., Platonov D. N., Petrosyan V. A. Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 363-364.
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TY - JOUR
DO - 10.1016/j.mencom.2014.11.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.018
TI - Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile
T2 - Mendeleev Communications
AU - Kokorekin, Vladimir Alekseevich
AU - Yanilkin, Vitaly Vasil'evich
AU - Morozov, Vladimir Ivanovich
AU - Tomilov, Yury Vasil'evich
AU - Platonov, Dmitry Nikolaevich
AU - Petrosyan, Vladimir Anushavanovich
PY - 2014
DA - 2014/10/30
PB - Mendeleev Communications
SP - 363-364
IS - 6
VL - 24
ER -
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@article{2014_Kokorekin,
author = {Vladimir Alekseevich Kokorekin and Vitaly Vasil'evich Yanilkin and Vladimir Ivanovich Morozov and Yury Vasil'evich Tomilov and Dmitry Nikolaevich Platonov and Vladimir Anushavanovich Petrosyan},
title = {Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.018},
number = {6},
pages = {363--364},
doi = {10.1016/j.mencom.2014.11.018}
}
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Kokorekin, Vladimir Alekseevich, et al. “Electrooxidation of potassium hepta(methoxycarbonyl)cycloheptatrienide in acetonitrile.” Mendeleev Communications, vol. 24, no. 6, Oct. 2014, pp. 363-364. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.018.

Abstract

The quasi-reversible one-electron electrooxidation of the 1,2,3,4,5,6,7-hepta(methoxy-carbonyl)cycloheptatrienide anion in MeCN at 22°C gives a radical whose ESR spectrum consists of seven lines with splittings from six protons with an intensity ratio of 1: 6: 15: 20: 15: 6: 1, which likely corresponds to a substituted bicyclo[3.2.0]heptadienyl structure.

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