Home / Publications / Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+

Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+

Alexander Sergeyevich Romanov 1
Alexander Sergeyevich Romanov
, 
Mikhail Mikhailovich Vinogradov 1
Mikhail Mikhailovich Vinogradov
, 
Dmitry Victorovich Muratov 1
Dmitry Victorovich Muratov
, 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
10.1016/j.mencom.2014.11.016
Published 2014-10-30
Communication , Volume 24, Issue 6, 358-359
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Romanov A. S. et al. Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+ // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 358-359.
GOST all authors (up to 50) Copy
Romanov A. S., Vinogradov M. M., Muratov D. V., Kudinov A. R. Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+ // Mendeleev Communications. 2014. Vol. 24. No. 6. pp. 358-359.
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TY - JOUR
DO - 10.1016/j.mencom.2014.11.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.016
TI - Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+
T2 - Mendeleev Communications
AU - Romanov, Alexander Sergeyevich
AU - Vinogradov, Mikhail Mikhailovich
AU - Muratov, Dmitry Victorovich
AU - Kudinov, Alexander Rudolfovich
PY - 2014
DA - 2014/10/30
PB - Mendeleev Communications
SP - 358-359
IS - 6
VL - 24
ER -
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@article{2014_Romanov,
author = {Alexander Sergeyevich Romanov and Mikhail Mikhailovich Vinogradov and Dmitry Victorovich Muratov and Alexander Rudolfovich Kudinov},
title = {Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.016},
number = {6},
pages = {358--359},
doi = {10.1016/j.mencom.2014.11.016}
}
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Romanov, Alexander Sergeyevich, et al. “Protonation of Cp*Fe(η5-C6H7) as a convenient procedure for the preparation of the valuable synthon [Cp*Fe(MeCN)3]+.” Mendeleev Communications, vol. 24, no. 6, Oct. 2014, pp. 358-359. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.11.016.

Abstract

The (cyclohexadienyl)iron complex Cp*Fe(η5-C6H7) obtained by a reaction of the cation [Cp*Fe(η6-C6H6)]+ with LiAlH4 reacts with HBF4·Et2O or TfOH in MeCN to afford the acetonitrile cation [Cp*Fe(MeCN)3]+ in a high yield. The structure of complex Cp*Fe(η5-C6H7) was determined by X-ray diffraction analysis.

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