Home / Publications / Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water

Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water

, 
Ludmila Viktorovna Andriyankova 1
Ludmila Viktorovna Andriyankova
, 
Anastasiya Grigor'evna Mal'kina 1
Anastasiya Grigor'evna Mal'kina
, 
Ol'ga Gennad'evna Volostnykh 1
Ol'ga Gennad'evna Volostnykh
, 
Lina Pavlovna Nikitina 1
Lina Pavlovna Nikitina
, 
Andrei Valer'evich Afonin 1
Andrei Valer'evich Afonin
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Lyudmila Vasil'evna Klyba 1
Lyudmila Vasil'evna Klyba
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2014.06.006
Published 2014-06-25
Communication , Volume 24, Issue 4, 209-210
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Belyaeva K. V. et al. Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 209-210.
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Belyaeva K. V., Andriyankova L. V., Mal'kina A. G., Volostnykh O. G., Nikitina L. P., Afonin A. V., Ushakov I. A., Klyba L. V., Trofimov B. A. Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 209-210.
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TY - JOUR
DO - 10.1016/j.mencom.2014.06.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.006
TI - Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water
T2 - Mendeleev Communications
AU - Belyaeva, Kseniya Vasil'evna
AU - Andriyankova, Ludmila Viktorovna
AU - Mal'kina, Anastasiya Grigor'evna
AU - Volostnykh, Ol'ga Gennad'evna
AU - Nikitina, Lina Pavlovna
AU - Afonin, Andrei Valer'evich
AU - Ushakov, Igor Alekseevich
AU - Klyba, Lyudmila Vasil'evna
AU - Trofimov, Boris Aleksandrovich
PY - 2014
DA - 2014/06/25
PB - Mendeleev Communications
SP - 209-210
IS - 4
VL - 24
ER -
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@article{2014_Belyaeva,
author = {Kseniya Vasil'evna Belyaeva and Ludmila Viktorovna Andriyankova and Anastasiya Grigor'evna Mal'kina and Ol'ga Gennad'evna Volostnykh and Lina Pavlovna Nikitina and Andrei Valer'evich Afonin and Igor Alekseevich Ushakov and Lyudmila Vasil'evna Klyba and Boris Aleksandrovich Trofimov},
title = {Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.006},
number = {4},
pages = {209--210},
doi = {10.1016/j.mencom.2014.06.006}
}
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Belyaeva, Kseniya Vasil'evna, et al. “Vinylation of trialkylamines with acyl- and cyanoacetylenes via C–N bond cleavage in the presence of water.” Mendeleev Communications, vol. 24, no. 4, Jun. 2014, pp. 209-210. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.006.

Abstract

Trialkylamines react with acyl- and cyanoacetylenes in the presence of water (90–100°C, 37–43h) to give functionalized N,N-dialkyl-vinylamines, the products of N-dealkylation of the starting amines, in 22–44% yields.

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