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Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix

Esfir Grigor'evna Baskir 1
Esfir Grigor'evna Baskir
, 
Dmitry Nikolaevich Platonov 1
Dmitry Nikolaevich Platonov
,  , 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1016/j.mencom.2014.06.002
Published 2014-06-25
Communication , Volume 24, Issue 4, 197-200
23
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Baskir E. G. et al. Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 197-200.
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Baskir E. G., Platonov D. N., Tomilov Y. V., Nefedov O. M. Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 197-200.
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TY - JOUR
DO - 10.1016/j.mencom.2014.06.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.002
TI - Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix
T2 - Mendeleev Communications
AU - Baskir, Esfir Grigor'evna
AU - Platonov, Dmitry Nikolaevich
AU - Tomilov, Yury Vasil'evich
AU - Nefedov, Oleg Matveevich
PY - 2014
DA - 2014/06/25
PB - Mendeleev Communications
SP - 197-200
IS - 4
VL - 24
ER -
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@article{2014_Baskir,
author = {Esfir Grigor'evna Baskir and Dmitry Nikolaevich Platonov and Yury Vasil'evich Tomilov and Oleg Matveevich Nefedov},
title = {Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.002},
number = {4},
pages = {197--200},
doi = {10.1016/j.mencom.2014.06.002}
}
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Baskir, Esfir Grigor'evna, et al. “Infrared-spectroscopic study of amino-substituted nitrilimines and their photochemical transformations in an argon matrix.” Mendeleev Communications, vol. 24, no. 4, Jun. 2014, pp. 197-200. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.002.

Abstract

3-Amino- and 3-(dimethyl)amino-1-methylnitrilimines were obtained by the photolysis (l = 254nm) of the corresponding 5-amino- and 5-(dimethyl)amino-2-methyltetrazoles in an argon matrix at 10K or in a gas phase at room temperature. They were characterized by IR spectroscopy and were found to be the primary products of the transformation; the prolonged UV irradiation of the matrix (l = 254nm) caused isomerization of the nitrilimines into diazirines.

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