Home / Publications / Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations

Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations

Maxim Olegovich Ratnikov 1
Maxim Olegovich Ratnikov
, 
Michael P Doyle 2
Michael P Doyle
10.1016/j.mencom.2014.06.001
Published 2014-06-25
Focus article , Volume 24, Issue 4, 187-196
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Ratnikov M. O., Doyle M. P. Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 187-196.
GOST all authors (up to 50) Copy
Ratnikov M. O., Doyle M. P. Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations // Mendeleev Communications. 2014. Vol. 24. No. 4. pp. 187-196.
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TY - JOUR
DO - 10.1016/j.mencom.2014.06.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.001
TI - Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations
T2 - Mendeleev Communications
AU - Ratnikov, Maxim Olegovich
AU - Doyle, Michael P
PY - 2014
DA - 2014/06/25
PB - Mendeleev Communications
SP - 187-196
IS - 4
VL - 24
ER -
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@article{2014_Ratnikov,
author = {Maxim Olegovich Ratnikov and Michael P Doyle},
title = {Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.001},
number = {4},
pages = {187--196},
doi = {10.1016/j.mencom.2014.06.001}
}
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Ratnikov, Maxim Olegovich, and Michael P Doyle. “Dirhodium caprolactamate and tert-butyl hydro- peroxide – a universal system for selective oxidations.” Mendeleev Communications, vol. 24, no. 4, Jun. 2014, pp. 187-196. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.06.001.
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Abstract

Oxidations with tert-butyl hydroperoxide (TBHP) catalyzed by dirhodium caprolactamate [Rh2(cap)4] provide mild and selective protocols for the oxidative Mannich reaction, conversion of secondary amines to imines, dearomatization of 4-substituted phenols, and oxyfunctionalization of allylic, benzylic, and propargylic positions. The dirhodium catalyst in combination with TBHP is a convenient platform for mechanistic investigations, and their uses point to a variety of directions for the future evolution of the field.

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