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Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction

Elizaveta Vladimirovna Larina 1
Elizaveta Vladimirovna Larina
, 
Anna Arkad'evna Kurokhtina 1
Anna Arkad'evna Kurokhtina
, 
10.1016/j.mencom.2014.03.010
Published 2014-02-21
Communication , Volume 24, Issue 2, 96-97
3
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Larina E. V., Kurokhtina A. A., Schmidt A. F. Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction // Mendeleev Communications. 2014. Vol. 24. No. 2. pp. 96-97.
GOST all authors (up to 50) Copy
Larina E. V., Kurokhtina A. A., Schmidt A. F. Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction // Mendeleev Communications. 2014. Vol. 24. No. 2. pp. 96-97.
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TY - JOUR
DO - 10.1016/j.mencom.2014.03.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.010
TI - Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction
T2 - Mendeleev Communications
AU - Larina, Elizaveta Vladimirovna
AU - Kurokhtina, Anna Arkad'evna
AU - Schmidt, Alexander Fedorovich
PY - 2014
DA - 2014/02/21
PB - Mendeleev Communications
SP - 96-97
IS - 2
VL - 24
ER -
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@article{2014_Larina,
author = {Elizaveta Vladimirovna Larina and Anna Arkad'evna Kurokhtina and Alexander Fedorovich Schmidt},
title = {Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.010},
number = {2},
pages = {96--97},
doi = {10.1016/j.mencom.2014.03.010}
}
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Larina, Elizaveta Vladimirovna, et al. “Approach to the Determination of Kinetic Order of Catalyst Deactivation: Observation of Unusual Kinetics in the Suzuki – Miyaura Reaction.” Mendeleev Communications, vol. 24, no. 2, Feb. 2014, pp. 96-97. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.010.

Abstract

Using of a new approach to estimate the kinetic orders of catalyst transformations in the Suzuki–Miyaura reaction allowed us to establish that the catalytic reaction and catalyst deactivation are of nearly first orders, and this fact contradicts the current view on the nature of an active catalyst.

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