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Synthesis and X-ray structure of C2-C84(22)(CF3)6

Natalia A Romanova 1
Natalia A Romanova
, 
Maria Andreevna Fritz 1
Maria Andreevna Fritz
, 
Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
10.1016/j.mencom.2014.03.003
Published 2014-02-21
Communication , Volume 24, Issue 2, 78-79
6
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Romanova N. A. et al. Synthesis and X-ray structure of C2-C84(22)(CF3)6 // Mendeleev Communications. 2014. Vol. 24. No. 2. pp. 78-79.
GOST all authors (up to 50) Copy
Romanova N. A., Fritz M. A., Tamm N. B., Troyanov S. I. Synthesis and X-ray structure of C2-C84(22)(CF3)6 // Mendeleev Communications. 2014. Vol. 24. No. 2. pp. 78-79.
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TY - JOUR
DO - 10.1016/j.mencom.2014.03.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.003
TI - Synthesis and X-ray structure of C2-C84(22)(CF3)6
T2 - Mendeleev Communications
AU - Romanova, Natalia A
AU - Fritz, Maria Andreevna
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2014
DA - 2014/02/21
PB - Mendeleev Communications
SP - 78-79
IS - 2
VL - 24
ER -
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@article{2014_Romanova,
author = {Natalia A Romanova and Maria Andreevna Fritz and Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {Synthesis and X-ray structure of C2-C84(22)(CF3)6},
journal = {Mendeleev Communications},
year = {2014},
volume = {24},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.003},
number = {2},
pages = {78--79},
doi = {10.1016/j.mencom.2014.03.003}
}
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MLA Copy
Romanova, Natalia A., et al. “Synthesis and X-ray structure of C2-C84(22)(CF3)6.” Mendeleev Communications, vol. 24, no. 2, Feb. 2014, pp. 78-79. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2014.03.003.

Abstract

C2-C84(22)(CF3)6 was isolated by HPLC from the products of trifluoromethylation of fullerene C84. Its molecular structure elucidated by single crystal X-ray diffraction has an addition pattern with a six-membered chain of para additions of CF3 groups. C2-C84(22)(CF3)6 is the most stable isomer on a pathway to the known C2 and D2 isomers of C84(22)(CF3)12; the molecular structure of the latter was refined with a better accuracy.

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