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Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands

Maxim V Tolstykh 1
Maxim V Tolstykh
, 
Kirill Petrovich Birin 2
Kirill Petrovich Birin
,  , 
Vitalii Yur'evich Kotov 1, 4
Vitalii Yur'evich Kotov
10.1016/j.mencom.2013.12.016
Published 2013-12-12
Communication , Volume 24, Issue 1, 47-49
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Tolstykh M. V. et al. Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands // Mendeleev Communications. 2013. Vol. 24. No. 1. pp. 47-49.
GOST all authors (up to 50) Copy
Tolstykh M. V., Birin K. P., Nelyubina Y. V., Kotov V. Y. Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands // Mendeleev Communications. 2013. Vol. 24. No. 1. pp. 47-49.
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TY - JOUR
DO - 10.1016/j.mencom.2013.12.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.016
TI - Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands
T2 - Mendeleev Communications
AU - Tolstykh, Maxim V
AU - Birin, Kirill Petrovich
AU - Nelyubina, Yulia Vladimirovna
AU - Kotov, Vitalii Yur'evich
PY - 2013
DA - 2013/12/12
PB - Mendeleev Communications
SP - 47-49
IS - 1
VL - 24
ER -
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@article{2013_Tolstykh,
author = {Maxim V Tolstykh and Kirill Petrovich Birin and Yulia Vladimirovna Nelyubina and Vitalii Yur'evich Kotov},
title = {Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands},
journal = {Mendeleev Communications},
year = {2013},
volume = {24},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.016},
number = {1},
pages = {47--49},
doi = {10.1016/j.mencom.2013.12.016}
}
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Tolstykh, Maxim V., et al. “Reorientation of ions in contact ion pairs as a factor increasing the intensity of outer-sphere charge transfer bands.” Mendeleev Communications, vol. 24, no. 1, Dec. 2013, pp. 47-49. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.016.

Abstract

The found increase in the extinction coefficients of ion pairs at the low dielectric permittivity of solutions in binary solvents depends on the nature of a nonpolar solvent, and it is related to not only the transformation of solvate-separated ion pairs into contact ones but also the reorientation of ions in the contact ion pairs.

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