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Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2013.12.007
Published 2013-12-12
Communication , Volume 24, Issue 1, 23-25
6
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Vasil'ev A. A., Zlotin S. G. Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids // Mendeleev Communications. 2013. Vol. 24. No. 1. pp. 23-25.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Zlotin S. G. Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids // Mendeleev Communications. 2013. Vol. 24. No. 1. pp. 23-25.
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TY - JOUR
DO - 10.1016/j.mencom.2013.12.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.007
TI - Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Zlotin, Sergei Grigorievich
PY - 2013
DA - 2013/12/12
PB - Mendeleev Communications
SP - 23-25
IS - 1
VL - 24
ER -
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@article{2013_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Sergei Grigorievich Zlotin},
title = {Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids},
journal = {Mendeleev Communications},
year = {2013},
volume = {24},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.007},
number = {1},
pages = {23--25},
doi = {10.1016/j.mencom.2013.12.007}
}
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Vasil'ev, Andrei Alexandrovich, and Sergei Grigorievich Zlotin. “Palladium-catalyzed allylation of malonic acid derivatives in heterogeneous systems containing ionic liquids.” Mendeleev Communications, vol. 24, no. 1, Dec. 2013, pp. 23-25. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.12.007.

Abstract

Palladium-catalyzed potassium carbonate-assisted reaction between diethyl malonate and allyl acetate in the presence of 1,3-dialkyl-imidazolium ionic liquids (ILs) as solvents or phase transfer catalysts affords major monoallylation product, whereas in the presence of 1,2,3-trialkylimidazolium or quaternary ammonium/phosphonium ILs diallylation product is preferably formed. These procedures are extended to some other CH-acids and allylic acetates.

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