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Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles

Valery Alexandrovich Dyatlov 1
Valery Alexandrovich Dyatlov
, 
Iskander Rustamovich Rustamov 1
Iskander Rustamovich Rustamov
, 
Tatiana Anatol'evna Grebeneva 1
Tatiana Anatol'evna Grebeneva
,  , 
Yuri Grigor'evich Gololobov 2
Yuri Grigor'evich Gololobov
, 
10.1016/j.mencom.2013.11.019
Published 2013-10-30
Communication , Volume 23, Issue 6, 356-357
7
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Dyatlov V. A. et al. Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles // Mendeleev Communications. 2013. Vol. 23. No. 6. pp. 356-357.
GOST all authors (up to 50) Copy
Dyatlov V. A., Rustamov I. R., Grebeneva T. A., Maleev V. I., Gololobov Y. G., Kireev V. V. Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles // Mendeleev Communications. 2013. Vol. 23. No. 6. pp. 356-357.
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TY - JOUR
DO - 10.1016/j.mencom.2013.11.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.11.019
TI - Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles
T2 - Mendeleev Communications
AU - Dyatlov, Valery Alexandrovich
AU - Rustamov, Iskander Rustamovich
AU - Grebeneva, Tatiana Anatol'evna
AU - Maleev, Victor Ivanovich
AU - Gololobov, Yuri Grigor'evich
AU - Kireev, Vyacheslav Vasil'evich
PY - 2013
DA - 2013/10/30
PB - Mendeleev Communications
SP - 356-357
IS - 6
VL - 23
ER -
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@article{2013_Dyatlov,
author = {Valery Alexandrovich Dyatlov and Iskander Rustamovich Rustamov and Tatiana Anatol'evna Grebeneva and Victor Ivanovich Maleev and Yuri Grigor'evich Gololobov and Vyacheslav Vasil'evich Kireev},
title = {Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.11.019},
number = {6},
pages = {356--357},
doi = {10.1016/j.mencom.2013.11.019}
}
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Dyatlov, Valery Alexandrovich, et al. “Synthesis of 2-cyanoacryloyl chloride and its interaction with O- and S-nucleophiles.” Mendeleev Communications, vol. 23, no. 6, Oct. 2013, pp. 356-357. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.11.019.

Keywords

2-cyanoacryloyl chloride
dithioester
esterification
fluorine thio-
polymer

Abstract

Reaction of 2-cyanoacrylic acid with oxalyl chloride gives quantitatively 2-cyanoacryloyl chloride capable of esterifying thiols and fluorinated alcohols.

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