Home / Publications / Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts

Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts

Vasiliy Georgievich Shtamburg 1
Vasiliy Georgievich Shtamburg
, 
Oleg Valer'ievich Shishkin 2
Oleg Valer'ievich Shishkin
, 
Roman Igorevich Zubatyuk 2
Roman Igorevich Zubatyuk
, 
Victor Vasil'evich Shtamburg 3
Victor Vasil'evich Shtamburg
, 
Alexander Valerievich Tsygankov 4
Alexander Valerievich Tsygankov
, 
Alexander Vladimirovich Mazepa 5
Alexander Vladimirovich Mazepa
, 
Gulnara Konstantinovna Kadorkina 6
Gulnara Konstantinovna Kadorkina
, 
Remir Grigorevich Kostyanovsky 6
Remir Grigorevich Kostyanovsky
1 Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
2 STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
3 Kharkov Institute of Ecology and Social Dependence, Kharkov, Ukraine
4 State Flight Academy of Ukraine, Kirovograd, Ukraine
5 A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
10.1016/j.mencom.2013.09.018
Published 2013-09-10
Communication , Volume 23, Issue 5, 289-291
6
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Shtamburg V. G. et al. Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts // Mendeleev Communications. 2013. Vol. 23. No. 5. pp. 289-291.
GOST all authors (up to 50) Copy
Shtamburg V. G., Shishkin O. V., Zubatyuk R. I., Shtamburg V. V., Tsygankov A. V., Mazepa A. V., Kadorkina G. K., Kostyanovsky R. G. Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts // Mendeleev Communications. 2013. Vol. 23. No. 5. pp. 289-291.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2013.09.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.09.018
TI - Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts
T2 - Mendeleev Communications
AU - Shtamburg, Vasiliy Georgievich
AU - Shishkin, Oleg Valer'ievich
AU - Zubatyuk, Roman Igorevich
AU - Shtamburg, Victor Vasil'evich
AU - Tsygankov, Alexander Valerievich
AU - Mazepa, Alexander Vladimirovich
AU - Kadorkina, Gulnara Konstantinovna
AU - Kostyanovsky, Remir Grigorevich
PY - 2013
DA - 2013/09/10
PB - Mendeleev Communications
SP - 289-291
IS - 5
VL - 23
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Shtamburg,
author = {Vasiliy Georgievich Shtamburg and Oleg Valer'ievich Shishkin and Roman Igorevich Zubatyuk and Victor Vasil'evich Shtamburg and Alexander Valerievich Tsygankov and Alexander Vladimirovich Mazepa and Gulnara Konstantinovna Kadorkina and Remir Grigorevich Kostyanovsky},
title = {Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.09.018},
number = {5},
pages = {289--291},
doi = {10.1016/j.mencom.2013.09.018}
}
MLA
Cite this
MLA Copy
Shtamburg, Vasiliy Georgievich, et al. “Synthesis and structure of N-alkoxyhydrazines and N-alkoxy-N’,N’,N’-trialkylhydrazinium salts.” Mendeleev Communications, vol. 23, no. 5, Sep. 2013, pp. 289-291. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.09.018.

Abstract

New types of 1,1,1-trialkyl-2-alkoxyhydrazinium chlorides and N-alkoxyhydrazines were obtained by reactions of N-chloro-N-alkoxy- ureas with trimethylamine or 1,4-diaza[2.2.2]bicyclooctane and by reactions of methyl N-chloro-N-methoxycarbamate with potassium salt of N-acetylbenzenesulfonylamide. The XRD studies of N,N’-bis(methoxycarbonyl)-N,N’-dimethoxyhydrazine, N’-methoxy- N’-methoxycarbonyl-N-acetylbenzenesulfonylhydrazide and 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate revealed the pyramidal configuration of the central nitrogen atoms in O–N–N geminal system, unusual elongation of N–N+ bond and shortening of N–OMe bond in 1,1,1-trimethyl-2-methoxyhydrazinium perchlorate.

References

1.
Shtamburg V.G., Tsygankov A.V., Shishkin O.V., Zubatyuk R.I., Uspensky B.V., Shtamburg V.V., Mazepa A.V., Kostyanovsky R.G.
Mendeleev Communications, 2012
2.
Shtamburg V.G., Tsygankov A.V., Shishkin O.V., Zubatyuk R.I., Shtamburg V.V., Gerasimenko M.V., Mazepa A.V., Kostyanovsky R.G.
Mendeleev Communications, 2012
3.
Geminal systems
Prokof'ev A.I., Rudchenko V.F., Ignatov S.M., Chervin I.I., Kostyanovskii R.G.
Russian Chemical Bulletin, 1989
4.
Geminal systems
Antipin M.Y., Struchkov Y.T., Rudchenko V.F., Ignatov S.M., Kostyanovskii R.G.
Russian Chemical Bulletin, 1989
8.
Structure, conformation, anomeric effects and rotational barriers in the HERON amides, N,N ′-diacyl-N,N ′-dialkoxyhydrazines
Glover S.A., Mo G., Rauk A., Tucker D.J., Turner P.
Journal of the Chemical Society Perkin Transactions 2, 1999
9.
Bimolecular reactions of mutagenic N-acetoxy-N-alkoxybenzamides and N-methylaniline
Campbell J.J., Glover S.A.
Journal of the Chemical Society Perkin Transactions 2, 1992
11.
Geminal systems. 16. Reactions of N-chloro-N-alkoxy-N-alkylamines with amines
Shtamburg V.G., Rudchenko V.F., Nasibov S.S., Chervin I.I., Pleshkova A.P., Kostyanovskii R.G.
Russian Chemical Bulletin, 1981
12.
Bimolecular Reactions of Mutagenic N-Acyloxy-N-alkoxybenzamides with Aromatic Amines
Campbell J.J., Glover S.A.
Journal of Chemical Research, 1999
13.
10.1016/j.mencom.2013.09.018_bib0065
Cambell
J. Chem. Res. (M), 1999
15.
Preparation and reactions of N,N'-diacyl-N,N'-dialkoxyhydrazines
Cooley J.H., Mosher M.W., Khan M.A.
Journal of the American Chemical Society, 1968
16.
Reactions of lead(IV). Part XXVI. Oxidation of some derivatives of hydroxylamine
Norman R.O., Purchase R., Thomas C.B.
Journal of the Chemical Society Perkin Transactions 1, 1972
17.
Spatial structure of N-?-chloroalkyllactams
Nasyrov D.M., Vereshchagin A.N.
Russian Chemical Bulletin, 1981
18.
Geminal systems. Communication 29. Reactions of N-chloro-N-methoxy-N?,N?-dimethylurea with N-nucleophiles
Rudchenko V.F., Shevchenko V.I., Kostyanovskii R.G.
Russian Chemical Bulletin, 1986
19.
Shtamburg V.G., Shishkin O.V., Zubatyuk R.I., Kravchenko S.V., Tsygankov A.V., Shtamburg V.V., Distanov V.B., Kostyanovsky R.G.
Mendeleev Communications, 2007
21.
Amino wagging and inversion in hydrazines
Tsuboi M., Overend J.
Journal of Molecular Spectroscopy, 1974
22.
Shtamburg V.G., Tsygankov A.V., Klots E.A., Fedyanin I.V., Lyssenko K.A., Kostyanovsky R.G.
Mendeleev Communications, 2006
23.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007