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Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ

Mikhail Igorevich Pleshchev 1
Mikhail Igorevich Pleshchev
, 
Margarita Alekseevna Epishina 1
Margarita Alekseevna Epishina
, 
Vadim Vadimovich Kachala 1
Vadim Vadimovich Kachala
, 
Vladimir Vladimirovich Kuznetsov 1
Vladimir Vladimirovich Kuznetsov
, 
Alexander Sergeyevich Goloveshkin 2
Alexander Sergeyevich Goloveshkin
, 
Ivan Sergeevich Bushmarinov 2
Ivan Sergeevich Bushmarinov
, 
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
10.1016/j.mencom.2013.07.009
Published 2013-07-11
Communication , Volume 23, Issue 4, 206-208
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Pleshchev M. I. et al. Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 206-208.
GOST all authors (up to 50) Copy
Pleshchev M. I., Epishina M. A., Kachala V. V., Kuznetsov V. V., Goloveshkin A. S., Bushmarinov I. S., Makhova N. N. Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 206-208.
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TY - JOUR
DO - 10.1016/j.mencom.2013.07.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.009
TI - Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ
T2 - Mendeleev Communications
AU - Pleshchev, Mikhail Igorevich
AU - Epishina, Margarita Alekseevna
AU - Kachala, Vadim Vadimovich
AU - Kuznetsov, Vladimir Vladimirovich
AU - Goloveshkin, Alexander Sergeyevich
AU - Bushmarinov, Ivan Sergeevich
AU - Makhova, Nina Nikolaevna
PY - 2013
DA - 2013/07/11
PB - Mendeleev Communications
SP - 206-208
IS - 4
VL - 23
ER -
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@article{2013_Pleshchev,
author = {Mikhail Igorevich Pleshchev and Margarita Alekseevna Epishina and Vadim Vadimovich Kachala and Vladimir Vladimirovich Kuznetsov and Alexander Sergeyevich Goloveshkin and Ivan Sergeevich Bushmarinov and Nina Nikolaevna Makhova},
title = {Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.009},
number = {4},
pages = {206--208},
doi = {10.1016/j.mencom.2013.07.009}
}
MLA
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Pleshchev, Mikhail Igorevich, et al. “Ionic liquid-promoted stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated in situ.” Mendeleev Communications, vol. 23, no. 4, Jul. 2013, pp. 206-208. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.009.

Abstract

Ionic liquids facilitate regio- and stereoselective [3 + 2] cycloaddition of 1-hetaryl-2-nitroethenes to azomethine imines generated catalytically from 6-Ar-1,5-diazabicyclo[3.1.0]hexanes in the presence of BF3 Et2O. The similar reaction is possible in MeCN only for azomethine imine with Ar = 2,4-(MeO)2C6H3 to give a mixture of two diastereomers.

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