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Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system

Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Nadezhda Victorovna Zorina 1
Nadezhda Victorovna Zorina
, 
Ol'ga Anatol'evna Tarasova 1
Ol'ga Anatol'evna Tarasova
, 
Igor Alekseevich Ushakov 1
Igor Alekseevich Ushakov
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2013.07.008
Published 2013-07-11
Communication , Volume 23, Issue 4, 204-205
9
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Schmidt E. Y. et al. Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 204-205.
GOST all authors (up to 50) Copy
Schmidt E. Y., Zorina N. V., Tarasova O. A., Ushakov I. A., Trofimov B. A. Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 204-205.
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TY - JOUR
DO - 10.1016/j.mencom.2013.07.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.008
TI - Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system
T2 - Mendeleev Communications
AU - Schmidt, Elena Yur'evna
AU - Zorina, Nadezhda Victorovna
AU - Tarasova, Ol'ga Anatol'evna
AU - Ushakov, Igor Alekseevich
AU - Trofimov, Boris Aleksandrovich
PY - 2013
DA - 2013/07/11
PB - Mendeleev Communications
SP - 204-205
IS - 4
VL - 23
ER -
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@article{2013_Schmidt,
author = {Elena Yur'evna Schmidt and Nadezhda Victorovna Zorina and Ol'ga Anatol'evna Tarasova and Igor Alekseevich Ushakov and Boris Aleksandrovich Trofimov},
title = {Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.008},
number = {4},
pages = {204--205},
doi = {10.1016/j.mencom.2013.07.008}
}
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Schmidt, Elena Yur'evna, et al. “Superbase-catalyzed addition of ketones to propargyl and allenyl ethers in the KOH (KOBut)/DMSO system.” Mendeleev Communications, vol. 23, no. 4, Jul. 2013, pp. 204-205. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.008.

Abstract

Alkyl (het)aryl ketones undergo nucleophilic addition to propargyl or allenyl ethers in the KOH (KOBut)/DMSO system at 100°C either at terminal (giving 1:2 adducts) or internal (giving 1:1 adducts) positions of the propargyl or allenyl fragment.

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