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Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes

Konstantin Igorevich Galkin 1
Konstantin Igorevich Galkin
, 
Fedor Mikhailovich Dolgushin 1
Fedor Mikhailovich Dolgushin
, 
Alexander Fedorovich Smol'yakov 1
Alexander Fedorovich Smol'yakov
, 
Ivan Alexandrovich Godovikov 1
Ivan Alexandrovich Godovikov
, 
Elena Andreevna Sergeeva 1
Elena Andreevna Sergeeva
, 
Igor Timofeevich Chizhevsky 1
Igor Timofeevich Chizhevsky
10.1016/j.mencom.2013.07.004
Published 2013-07-11
Communication , Volume 23, Issue 4, 193-195
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Galkin K. I. et al. Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 193-195.
GOST all authors (up to 50) Copy
Galkin K. I., Dolgushin F. M., Smol'yakov A. F., Godovikov I. A., Sergeeva E. A., Chizhevsky I. T. Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 193-195.
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TY - JOUR
DO - 10.1016/j.mencom.2013.07.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.004
TI - Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes
T2 - Mendeleev Communications
AU - Galkin, Konstantin Igorevich
AU - Dolgushin, Fedor Mikhailovich
AU - Smol'yakov, Alexander Fedorovich
AU - Godovikov, Ivan Alexandrovich
AU - Sergeeva, Elena Andreevna
AU - Chizhevsky, Igor Timofeevich
PY - 2013
DA - 2013/07/11
PB - Mendeleev Communications
SP - 193-195
IS - 4
VL - 23
ER -
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@article{2013_Galkin,
author = {Konstantin Igorevich Galkin and Fedor Mikhailovich Dolgushin and Alexander Fedorovich Smol'yakov and Ivan Alexandrovich Godovikov and Elena Andreevna Sergeeva and Igor Timofeevich Chizhevsky},
title = {Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.004},
number = {4},
pages = {193--195},
doi = {10.1016/j.mencom.2013.07.004}
}
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Galkin, Konstantin Igorevich, et al. “Mixed-ligand di-µ-chloro-bridged Rhodium Dimers as Key Intermediates in the Synthesis of Acyclic (p-allyl)-closo-rhodacarboranes.” Mendeleev Communications, vol. 23, no. 4, Jul. 2013, pp. 193-195. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.004.

Abstract

The mixed-ligand di-m-chloro-bridged rhodium dimers [(?2-C8H14)(?4-2-methylbuta-1,3-diene)Rh(µ-Cl)]2 and [(?2-C8H14)(?4-2,3- dimethylbuta-1,3-diene)Rh(µ-Cl)]2 were synthesized and characterized. These compounds are key precursors in the preparative syn- thesis of the acyclic (p-allyl)-closo-rhodacarborane complexes [3-{p-(R”-allyl)}-1-R-2-R’-closo-3,1,2-RhC2B9H9], which were obtained earlierviathe one-pot metallation of the K+ salts of the [7-R-8-R’-nido-7,8-C2B9H10]– anions with [(?2-C8H14)4Rh2(µ-Cl)2] in the presence of substituted buta-1,3-diene ligands.

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