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Total synthesis of strobilurin B

Viktor Aleksandrovich Popovsky 1
Viktor Aleksandrovich Popovsky
, 
Andrei Valentinovich Stepanov 1
Andrei Valentinovich Stepanov
, 
Natalia Yakovlevna Grigorieva 1
Natalia Yakovlevna Grigorieva
10.1016/j.mencom.2013.07.003
Published 2013-07-11
Communication , Volume 23, Issue 4, 190-192
3
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Popovsky V. A., Stepanov A. V., Grigorieva N. Y. Total synthesis of strobilurin B // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 190-192.
GOST all authors (up to 50) Copy
Popovsky V. A., Stepanov A. V., Grigorieva N. Y. Total synthesis of strobilurin B // Mendeleev Communications. 2013. Vol. 23. No. 4. pp. 190-192.
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TY - JOUR
DO - 10.1016/j.mencom.2013.07.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.003
TI - Total synthesis of strobilurin B
T2 - Mendeleev Communications
AU - Popovsky, Viktor Aleksandrovich
AU - Stepanov, Andrei Valentinovich
AU - Grigorieva, Natalia Yakovlevna
PY - 2013
DA - 2013/07/11
PB - Mendeleev Communications
SP - 190-192
IS - 4
VL - 23
ER -
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@article{2013_Popovsky,
author = {Viktor Aleksandrovich Popovsky and Andrei Valentinovich Stepanov and Natalia Yakovlevna Grigorieva},
title = {Total synthesis of strobilurin B},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.003},
number = {4},
pages = {190--192},
doi = {10.1016/j.mencom.2013.07.003}
}
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Popovsky, Viktor Aleksandrovich, et al. “Total synthesis of strobilurin B.” Mendeleev Communications, vol. 23, no. 4, Jul. 2013, pp. 190-192. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.07.003.

Abstract

A nine-stage total synthesis of strobilurin B has been carried out with an overall yield of 5.5%. The key step was the stereocontrolled condensation between N-tert-butylaldimine and α,β-enal followed by reduction of the formyl group into methyl.

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