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Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes

Vladislav Yurievich Korotaev 1
Vladislav Yurievich Korotaev
, 
Alexey Yurievich Barkov 1
Alexey Yurievich Barkov
, 
Anna Aleksandrovna Sokovnina 1
Anna Aleksandrovna Sokovnina
, 
Vyacheslav Yakovlevich Sosnovskikh 1
Vyacheslav Yakovlevich Sosnovskikh
10.1016/j.mencom.2013.05.010
Published 2013-05-08
Communication , Volume 23, Issue 3, 150-152
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Korotaev V. Y. et al. Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 150-152.
GOST all authors (up to 50) Copy
Korotaev V. Y., Barkov A. Y., Sokovnina A. A., Sosnovskikh V. Y. Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 150-152.
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TY - JOUR
DO - 10.1016/j.mencom.2013.05.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.010
TI - Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes
T2 - Mendeleev Communications
AU - Korotaev, Vladislav Yurievich
AU - Barkov, Alexey Yurievich
AU - Sokovnina, Anna Aleksandrovna
AU - Sosnovskikh, Vyacheslav Yakovlevich
PY - 2013
DA - 2013/05/08
PB - Mendeleev Communications
SP - 150-152
IS - 3
VL - 23
ER -
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@article{2013_Korotaev,
author = {Vladislav Yurievich Korotaev and Alexey Yurievich Barkov and Anna Aleksandrovna Sokovnina and Vyacheslav Yakovlevich Sosnovskikh},
title = {Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.010},
number = {3},
pages = {150--152},
doi = {10.1016/j.mencom.2013.05.010}
}
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Korotaev, Vladislav Yurievich, et al. “Highly Regio-and Stereoselective Addition of Ethyl 3-Aminobut-2-enoates to 2-substituted 3-nitro-2H-chromenes.” Mendeleev Communications, vol. 23, no. 3, May. 2013, pp. 150-152. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.010.

Abstract

Ethyl 3-aminobut-2-enoates MeC(NHR)=CHCO2Et (R = H, Me, Bn) whose reaction site is C(2) atom add to 2-R-3-nitro-2H-chromenes at their C(4) atom to give the corresponding trans,trans-2,3,4-trisubstituted chromanes. Analogous substrates MeC(NR2)=CHCO2Et (NR2 is piperidin-1-yl or morpholin-4-yl) react by their C(4) methyl group to afford cis,trans-2,3,4-trisubstituted chromanes. The stereochemistry of the products was established by X-ray diffraction analysis.

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