Home / Publications / Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2

Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2

Ekaterina Alexandrovna Trofimova 1
Ekaterina Alexandrovna Trofimova
, 
Alexey Borisovich Dobrynin 1
Alexey Borisovich Dobrynin
, 
Tatiana Pavlovna Gerasimova 1
Tatiana Pavlovna Gerasimova
, 
Sergey Alexandrovich Katsyuba 1
Sergey Alexandrovich Katsyuba
,  , 
Dmitry Grigorievich Yakhvarov 1, 2
Dmitry Grigorievich Yakhvarov
10.1016/j.mencom.2013.05.004
Published 2013-05-08
Communication , Volume 23, Issue 3, 135-136
8
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Trofimova E. A. et al. Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2 // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 135-136.
GOST all authors (up to 50) Copy
Trofimova E. A., Dobrynin A. B., Gerasimova T. P., Katsyuba S. A., Sinyashin O. G., Yakhvarov D. G. Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2 // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 135-136.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2013.05.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.004
TI - Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2
T2 - Mendeleev Communications
AU - Trofimova, Ekaterina Alexandrovna
AU - Dobrynin, Alexey Borisovich
AU - Gerasimova, Tatiana Pavlovna
AU - Katsyuba, Sergey Alexandrovich
AU - Sinyashin, Oleg Gerol'dovich
AU - Yakhvarov, Dmitry Grigorievich
PY - 2013
DA - 2013/05/08
PB - Mendeleev Communications
SP - 135-136
IS - 3
VL - 23
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Trofimova,
author = {Ekaterina Alexandrovna Trofimova and Alexey Borisovich Dobrynin and Tatiana Pavlovna Gerasimova and Sergey Alexandrovich Katsyuba and Oleg Gerol'dovich Sinyashin and Dmitry Grigorievich Yakhvarov},
title = {Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.004},
number = {3},
pages = {135--136},
doi = {10.1016/j.mencom.2013.05.004}
}
MLA
Cite this
MLA Copy
Trofimova, Ekaterina Alexandrovna, et al. “Synthesis, X-ray crystal structure and quantum-chemical study of new dinuclear cobalt complex {Co2[mmm-O2P(H)Mes]2(bpy)4}Br2.” Mendeleev Communications, vol. 23, no. 3, May. 2013, pp. 135-136. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.004.

Keywords

2,2'-bipyridine
bridging phosphinate ligands
dinuclear cobalt complexes
quantum-chemical study
X-Ray crystal structure

Abstract

The reaction of cobalt dibromide hexahydrate with 2,2’-bipyridine (bpy) and mesitylphosphinic acid MesP(O)(OH)H (Mes = = 2,4,6-trimethylphenyl) under solvothermal synthesis conditions leads to a new dinuclear cobalt(ii) complex {Co2[µ-O2P(H)Mes]2- (bpy)4}Br2 formed by two bridging {µ-O2P(H)Mes}– ligands. X-ray crystal structure analysis of the complex displayed that cobalt ions have distorted octahedral coordination and are doubly bridged by two mesitylphosphinato ligands.

References

1.
Thermal stability of coordination polymers
Tomic E.A.
Journal of Applied Polymer Science, 1965
3.
Metal-organic frameworks
James S.L.
Chemical Society Reviews, 2003
5.
Nanoscale borromean rings.
Cantrill S.J., Chichak K.S., Peters A.J., Stoddart J.F.
Accounts of Chemical Research, 2004
6.
Crystal engineering, where from? Where to?
Braga D.
Chemical Communications, 2003
7.
High-Symmetry Coordination Cages via Self-Assembly
Seidel S.R., Stang P.J.
Accounts of Chemical Research, 2002
8.
Crystallized Frameworks with Giant Pores:  Are There Limits to the Possible?
Férey G., Mellot-Draznieks C., Serre C., Millange F.
Accounts of Chemical Research, 2005
9.
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage
Eddaoudi M., Kim J., Rosi N., Vodak D., Wachter J., O'Keeffe M., Yaghi O.M.
Science, 2002
10.
Hydrogen Storage in Microporous Metal-Organic Frameworks
Rosi N.L., Eckert J., Eddaoudi M., Vodak D.T., Kim J., O'Keeffe M., Yaghi O.M.
Science, 2003
11.
Highly Interpenetrated Metal-Organic Frameworks for Hydrogen Storage
Kesanli B., Cui Y., Smith M.R., Bittner E.W., Bockrath B.C., Lin W.
Angewandte Chemie - International Edition, 2005
13.
Chemistry and Physics of Supramolecular Magnetic Materials
Kahn O.
Accounts of Chemical Research, 2000
14.
A homochiral metal–organic porous material for enantioselective separation and catalysis
Seo J.S., Whang D., Lee H., Jun S.I., Oh J., Jeon Y.J., Kim K.
Nature, 2000
17.
Burlov A.S., Antsyshkina A.S., Sadikov G.G., Zubenko A.A., Mashchenko S.A., Vasilchenko I.S., Sergienko V.S., Garnovskii A.D., Minkin V.I.
Mendeleev Communications, 2011
19.
Nonlinear Optically Active Polymeric Coordination Networks Based on Metal m-Pyridylphosphonates
Ayyappan P., Evans O.R., Cui Y., Wheeler K.A., Lin W.
Inorganic Chemistry, 2002
20.
Polymer photovoltaic cells by using manganese phthalocyanine derivative
Shen Y., Zheng F., Cheng W., Gu F., Zhang J., Xia Y.
Semiconductor Science and Technology, 2010
22.
Binuclear Metallohydrolases.
Wilcox D.E.
Chemical Reviews, 1996
25.
Biosynthesis of the thiazole moiety of thiamin pyrophosphate (vitamin B1).
Park J., Dorrestein P.C., Zhai H., Kinsland C., McLafferty F.W., Begley T.P.
Biochemistry, 2003
26.
The Biochemistry of the Nucleic Acids
Adams R.L., Knowler J.T., Leader D.P.
1992
28.
J. M. Berg, J.L. Tymoczko and L. Stryer, Biochemistry, W.H. Freeman, New York, 2008, p. 1026.
29.
Kinetics of metal-catalyzed adenosine triphosphate dephosphorylation
Spiro T.G., Kjellstrom W.A., Zeydel M., Butow R.A.
Biochemistry, 1968
31.
Synthesis and Characterization of a Novel Cyclic Aluminophosphinate:  Structure and Solid-State NMR Study
Azaïs T., Bonhomme-Coury L., Vaissermann J., Bertani P., Hirschinger J., Maquet J., Bonhomme C.
Inorganic Chemistry, 2002
32.
Structural Diversity in Zinc Phosphates and Phosphinates: Observation of a Lattice Water Dimer Sandwiched Between Phosphoryl Oxygen Atoms
Pothiraja R., Shanmugan S., Walawalkar M.G., Nethaji M., Butcher R.J., Murugavel R.
European Journal of Inorganic Chemistry, 2008
33.
New dinuclear nickel(II) complexes: synthesis, structure, electrochemical, and magnetic properties.
Yakhvarov D., Trofimova E., Sinyashin O., Kataeva O., Budnikova Y., Lönnecke P., Hey-Hawkins E., Petr A., Krupskaya Y., Kataev V., Klingeler R., Büchner B.
Inorganic Chemistry, 2011
34.
Engineering a Metal–Organic Framework Catalyst by Using Postsynthetic Modification
Tanabe K., Cohen S.
Angewandte Chemie - International Edition, 2009
37.
Covalent radii revisited
Cordero B., Gómez V., Platero-Prats A.E., Revés M., Echeverría J., Cremades E., Barragán F., Alvarez S.
Dalton Transactions, 2008