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Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands

Evgeniya Aleksandrovna Trifonova 1
Evgeniya Aleksandrovna Trifonova
, 
Natalia Leonidovna Loskutova 1
Natalia Leonidovna Loskutova
,  ,  , 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
10.1016/j.mencom.2013.05.003
Published 2013-05-08
Communication , Volume 23, Issue 3, 133-134
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Trifonova E. A. et al. Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 133-134.
GOST all authors (up to 50) Copy
Trifonova E. A., Loskutova N. L., Perekalin D. S., Nelyubina Y. V., Kudinov A. R. Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands // Mendeleev Communications. 2013. Vol. 23. No. 3. pp. 133-134.
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TY - JOUR
DO - 10.1016/j.mencom.2013.05.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.003
TI - Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands
T2 - Mendeleev Communications
AU - Trifonova, Evgeniya Aleksandrovna
AU - Loskutova, Natalia Leonidovna
AU - Perekalin, Dmitrii Sergeevich
AU - Nelyubina, Yulia Vladimirovna
AU - Kudinov, Alexander Rudolfovich
PY - 2013
DA - 2013/05/08
PB - Mendeleev Communications
SP - 133-134
IS - 3
VL - 23
ER -
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@article{2013_Trifonova,
author = {Evgeniya Aleksandrovna Trifonova and Natalia Leonidovna Loskutova and Dmitrii Sergeevich Perekalin and Yulia Vladimirovna Nelyubina and Alexander Rudolfovich Kudinov},
title = {Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.003},
number = {3},
pages = {133--134},
doi = {10.1016/j.mencom.2013.05.003}
}
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Trifonova, Evgeniya Aleksandrovna, et al. “Synthesis and reactivity of the cyclohexadienyl ruthenium complex [(hhh5-C6H7)Ru(MeCN)3]+ with labile acetonitrile ligands.” Mendeleev Communications, vol. 23, no. 3, May. 2013, pp. 133-134. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.05.003.

Abstract

The UV irradiation of [(h5-C6H7)Ru(C6H6)]+ in MeCN gives the title complex, in which acetonitrile ligands are readily replaced by cyclopentadienide and tricarbollide anions; the structure of the tricarbollide derivative 1-(h5-C6H7)-12-ButNH-1,2,4,12-RuC3B8H10 was established by X-ray diffraction analysis.

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