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Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface

Vladimir Nikolaevich Losev 1
Vladimir Nikolaevich Losev
, 
Elena Vasil'evna Buiko 1
Elena Vasil'evna Buiko
, 
Anatoly Konstantinovich Trofimtchuk 2
Anatoly Konstantinovich Trofimtchuk
, 
Nikolay Gennad'evich Maksimov 3
Nikolay Gennad'evich Maksimov
1 Research Engineering Centre ''Kristall'', Krasnoyarsk, Russian Federation
2 Department of Chemistry, T.G. Shevchenko Kiev National University, Kiev, Ukraine
10.1016/j.mencom.2013.03.012
Published 2013-03-06
Communication , Volume 23, Issue 2, 90-91
2
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Losev V. N. et al. Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 90-91.
GOST all authors (up to 50) Copy
Losev V. N., Buiko E. V., Trofimtchuk A. K., Maksimov N. G. Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 90-91.
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TY - JOUR
DO - 10.1016/j.mencom.2013.03.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.012
TI - Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface
T2 - Mendeleev Communications
AU - Losev, Vladimir Nikolaevich
AU - Buiko, Elena Vasil'evna
AU - Trofimtchuk, Anatoly Konstantinovich
AU - Maksimov, Nikolay Gennad'evich
PY - 2013
DA - 2013/03/06
PB - Mendeleev Communications
SP - 90-91
IS - 2
VL - 23
ER -
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@article{2013_Losev,
author = {Vladimir Nikolaevich Losev and Elena Vasil'evna Buiko and Anatoly Konstantinovich Trofimtchuk and Nikolay Gennad'evich Maksimov},
title = {Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.012},
number = {2},
pages = {90--91},
doi = {10.1016/j.mencom.2013.03.012}
}
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Losev, Vladimir Nikolaevich, et al. “Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface.” Mendeleev Communications, vol. 23, no. 2, Mar. 2013, pp. 90-91. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.012.

Abstract

The sorption characteristics and diffuse reflectance and EPR spectra of osmium surface complexes showed that Os8+ and Os6+ in OsO4 and K2[OsO2Cl4], respectively, react with mercaptopropyl groups, whereas Os4+ in K2[OsCl6] reacts with aminopropyl groups covalently bound to a silica gel surface.

References

5.
Sintez kompleksnykh soedinenii metallov platinovoi gruppy (Synthesis of Complex Compounds of Platinum Group Metals), Manual, Nauka, Moscow, 1964, p. 8.(in Russian).
6.
Z. Marchenko, Fotometricheskoe opredelenie elementov (Photometric Determination of Elements), Mir, Moscow, 1971 (in Russian).
7.
10.1016/j.mencom.2013.03.012_bib0035
Losev
Zh. Anal. Khim., 2004
8.
10.1016/j.mencom.2013.03.012_bib0040
Ivanov
Zh. Anal. Khim., 1985
9.
10.1016/j.mencom.2013.03.012_bib0045
Trofimchuk
Zh. Neorg. Khim., 2005
10.
Complex hyperfine structures in microwave spectra of covalent iridium compounds
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1954
11.
Spin Resonance of Transition Metal Ions in Corundum
Geschwind S., Remeika J.P.
Journal of Applied Physics, 1962