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Synthesis of four-membered bissilylene-linked bisamidines

Jian-Wei Mao 1
Jian-Wei Mao
, 
Tao Wang 1
Tao Wang
, 
Rui-Qin Liu 1
Rui-Qin Liu
, 
Sheng-Di Bai 1
Sheng-Di Bai
, 
Jian-Ping Guo 2
Jian-Ping Guo
, 
Dian-Sheng Liu 1
Dian-Sheng Liu
2 Solid Wastes Resource Utilization and Energy Saving Building Materials State Key Laboratory, Shijingshan District, Beijing, P. R. China
10.1016/j.mencom.2013.03.010
Published 2013-03-06
Communication , Volume 23, Issue 2, 86-87
4
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Mao J. et al. Synthesis of four-membered bissilylene-linked bisamidines // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 86-87.
GOST all authors (up to 50) Copy
Mao J., Wang T., Liu R., Bai S., Guo J., Liu D. Synthesis of four-membered bissilylene-linked bisamidines // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 86-87.
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TY - JOUR
DO - 10.1016/j.mencom.2013.03.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.010
TI - Synthesis of four-membered bissilylene-linked bisamidines
T2 - Mendeleev Communications
AU - Mao, Jian-Wei
AU - Wang, Tao
AU - Liu, Rui-Qin
AU - Bai, Sheng-Di
AU - Guo, Jian-Ping
AU - Liu, Dian-Sheng
PY - 2013
DA - 2013/03/06
PB - Mendeleev Communications
SP - 86-87
IS - 2
VL - 23
ER -
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@article{2013_Mao,
author = {Jian-Wei Mao and Tao Wang and Rui-Qin Liu and Sheng-Di Bai and Jian-Ping Guo and Dian-Sheng Liu},
title = {Synthesis of four-membered bissilylene-linked bisamidines},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.010},
number = {2},
pages = {86--87},
doi = {10.1016/j.mencom.2013.03.010}
}
MLA
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MLA Copy
Mao, Jian-Wei, et al. “Synthesis of four-membered bissilylene-linked bisamidines.” Mendeleev Communications, vol. 23, no. 2, Mar. 2013, pp. 86-87. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.010.

Abstract

Reaction of dilithium derivatives of N,N’-(dimethylsilanediyl)diamines, Me2Si[N(Li)R]2 with benzonitrile followed by treatment with Me2SiCl2 afforded 1,3-bis[1-(N-R-imino)-1-phenylmethyl]-1,3,2,4-diazadisiletidines, the neutral four-membered bissilylene-linked bisamidines, whose structure was established by X-ray diffraction.

References

1.
The coordination chemistry of the amidine ligand
Barker J., Kilner M.
Coordination Chemistry Reviews, 1994
9.
Dinuclear Chlorido‐, Alkyl(chlorido)‐, and Hydridoyttrium Complexes Supported by μ‐Bridging‐Silyl‐Linked Bis(amidinate) Ligands
Skvortsov G.G., Tolpyguin A.O., Fukin G.K., Cherkasov A.V., Trifonov A.A.
European Journal of Inorganic Chemistry, 2010
16.
Dianionic amidinates at silicon and germanium centers: Four-, six- and eight-membered rings
Segmüller T., Schlüter P.A., Drees M., Schier A., Nogai S., Mitzel N.W., Straßner T., Karsch H.H.
Journal of Organometallic Chemistry, 2007
19.
Novel neutral hexacoordinate silicon(iv) complexes with two bidentate monoanionic benzamidinato ligands
Junold K., Burschka C., Bertermann R., Tacke R.
Dalton Transactions, 2010