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Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Ilya Vladimirovich Kuchurov 1
Ilya Vladimirovich Kuchurov
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2013.03.009
Published 2013-03-06
Communication , Volume 23, Issue 2, 84-85
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Vasil'ev A. A., Kuchurov I. V., Zlotin S. G. Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 84-85.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Kuchurov I. V., Zlotin S. G. Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems // Mendeleev Communications. 2013. Vol. 23. No. 2. pp. 84-85.
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TY - JOUR
DO - 10.1016/j.mencom.2013.03.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.009
TI - Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Kuchurov, Ilya Vladimirovich
AU - Zlotin, Sergei Grigorievich
PY - 2013
DA - 2013/03/06
PB - Mendeleev Communications
SP - 84-85
IS - 2
VL - 23
ER -
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@article{2013_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Ilya Vladimirovich Kuchurov and Sergei Grigorievich Zlotin},
title = {Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.009},
number = {2},
pages = {84--85},
doi = {10.1016/j.mencom.2013.03.009}
}
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Vasil'ev, Andrei Alexandrovich, et al. “Tsuji–Trost allylation of CH acids in supercritical carbon dioxide: advantages and problems.” Mendeleev Communications, vol. 23, no. 2, Mar. 2013, pp. 84-85. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.03.009.

Abstract

The Pd(PPh3)4-catalyzed reaction between a-cyano or b-oxo carboxylates and allyl acetate in supercritical carbon dioxide with the K2CO3–18-crown-6 system as a base affords exhaustive allylation products in high yields, whereas malononitrile and acetylacetone of higher CH acidity form the mixtures of mono- and diallylated derivatives in moderate yields.

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