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Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen

Yuri Ilyich Murinov 1
Yuri Ilyich Murinov
, 
Stanislav Anatol'evich Grabovskiy 1
Stanislav Anatol'evich Grabovskiy
, 
Regina Maratovna Islamova 1
Regina Maratovna Islamova
, 
Al'bina Rasilevna Kuramshina 1
Al'bina Rasilevna Kuramshina
, 
Natalia Nurullovna Kabal'nova 1
Natalia Nurullovna Kabal'nova
10.1016/j.mencom.2013.01.020
Published 2013-01-03
Communication , Volume 23, Issue 1, 53-55
13
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Murinov Y. I. et al. Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 53-55.
GOST all authors (up to 50) Copy
Murinov Y. I., Grabovskiy S. A., Islamova R. M., Kuramshina A. R., Kabal'nova N. N. Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 53-55.
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TY - JOUR
DO - 10.1016/j.mencom.2013.01.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.020
TI - Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen
T2 - Mendeleev Communications
AU - Murinov, Yuri Ilyich
AU - Grabovskiy, Stanislav Anatol'evich
AU - Islamova, Regina Maratovna
AU - Kuramshina, Al'bina Rasilevna
AU - Kabal'nova, Natalia Nurullovna
PY - 2013
DA - 2013/01/03
PB - Mendeleev Communications
SP - 53-55
IS - 1
VL - 23
ER -
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@article{2013_Murinov,
author = {Yuri Ilyich Murinov and Stanislav Anatol'evich Grabovskiy and Regina Maratovna Islamova and Al'bina Rasilevna Kuramshina and Natalia Nurullovna Kabal'nova},
title = {Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.020},
number = {1},
pages = {53--55},
doi = {10.1016/j.mencom.2013.01.020}
}
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Murinov, Yuri Ilyich, et al. “Mechanism of Methyl Methacrylate Polymerization Initiated by Benzoyl Peroxide and Ferrocene in the Presence of Oxygen.” Mendeleev Communications, vol. 23, no. 1, Jan. 2013, pp. 53-55. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.020.

Keywords

[μ-(peroxy-O:O′)]di-ferrocenium
benzoyl peroxide
ferrocene
ferrocenium radical-cation
oligomeric reaction center

Abstract

The role of the ferrocenium radical cation and Cp2Fe+–O• radical in the initiation of methyl methacrylate polymerization in the absence and presence of oxygen was demonstrated.

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