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KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions

Galina Valentinovna Kryshtal 1
Galina Valentinovna Kryshtal
, 
Galina Mikhailovna Zhdankina 1
Galina Mikhailovna Zhdankina
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2013.01.008
Published 2013-01-03
Communication , Volume 23, Issue 1, 24-25
3
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Kryshtal G. V., Zhdankina G. M., Zlotin S. G. KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 24-25.
GOST all authors (up to 50) Copy
Kryshtal G. V., Zhdankina G. M., Zlotin S. G. KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 24-25.
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TY - JOUR
DO - 10.1016/j.mencom.2013.01.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.008
TI - KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions
T2 - Mendeleev Communications
AU - Kryshtal, Galina Valentinovna
AU - Zhdankina, Galina Mikhailovna
AU - Zlotin, Sergei Grigorievich
PY - 2013
DA - 2013/01/03
PB - Mendeleev Communications
SP - 24-25
IS - 1
VL - 23
ER -
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@article{2013_Kryshtal,
author = {Galina Valentinovna Kryshtal and Galina Mikhailovna Zhdankina and Sergei Grigorievich Zlotin},
title = {KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.008},
number = {1},
pages = {24--25},
doi = {10.1016/j.mencom.2013.01.008}
}
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Kryshtal, Galina Valentinovna, et al. “KOH-Promoted Synthesis of Oxirane Functional Derivatives from Diethyl Bromomalonate and Aldehydes under Phase-Transfer Catalysis Conditions.” Mendeleev Communications, vol. 23, no. 1, Jan. 2013, pp. 24-25. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.008.

Abstract

The Darzens condensation of diethyl bromomalonate with aromatic or isoprenoid aldehydes under heterogeneous conditions (KOH/MeCN) in the presence of Bu4NPF6 as a recoverable phase-transfer catalyst afforded the corresponding diethyl 3-R-oxirane-2,2-dicarboxylates in high yields.

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