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The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles

, 
Rinat Faritovich Salikov 1
Rinat Faritovich Salikov
, 
Dmitry Nikolaevich Platonov 1
Dmitry Nikolaevich Platonov
, 
Dmitry L'vovich Lipilin 1
Dmitry L'vovich Lipilin
, 
Aleksandr Ephimovna Frumkin 1
Aleksandr Ephimovna Frumkin
10.1016/j.mencom.2013.01.007
Published 2013-01-03
Communication , Volume 23, Issue 1, 22-23
13
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Tomilov Y. V. et al. The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 22-23.
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Tomilov Y. V., Salikov R. F., Platonov D. N., Lipilin D. L., Frumkin A. E. The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles // Mendeleev Communications. 2013. Vol. 23. No. 1. pp. 22-23.
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TY - JOUR
DO - 10.1016/j.mencom.2013.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.007
TI - The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles
T2 - Mendeleev Communications
AU - Tomilov, Yury Vasil'evich
AU - Salikov, Rinat Faritovich
AU - Platonov, Dmitry Nikolaevich
AU - Lipilin, Dmitry L'vovich
AU - Frumkin, Aleksandr Ephimovna
PY - 2013
DA - 2013/01/03
PB - Mendeleev Communications
SP - 22-23
IS - 1
VL - 23
ER -
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@article{2013_Tomilov,
author = {Yury Vasil'evich Tomilov and Rinat Faritovich Salikov and Dmitry Nikolaevich Platonov and Dmitry L'vovich Lipilin and Aleksandr Ephimovna Frumkin},
title = {The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles},
journal = {Mendeleev Communications},
year = {2013},
volume = {23},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.007},
number = {1},
pages = {22--23},
doi = {10.1016/j.mencom.2013.01.007}
}
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MLA Copy
Tomilov, Yury Vasil'evich, et al. “The Cyclopropyliminium Rearrangement of Cyclopropylthiazoles.” Mendeleev Communications, vol. 23, no. 1, Jan. 2013, pp. 22-23. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2013.01.007.

Abstract

2-Cyclopropylthiazole hydrobromides undergo iminocyclopropane-pyrroline rearrangement in a melt to give the corresponding fused heterocycles, viz. 6,7-dihydro-5H-pyrrolo[2,1-b]thiazol-4-ium bromides. 2-Alkyl- and 2-aryl-4-cyclopropylthiazoles transform into analogous fused heterocycles as hydroiodides and noticeably longer.

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