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Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures

Kirill Petrovich Birin 1
Kirill Petrovich Birin
, 
Dmitry Sergeevich Dunin 2
Dmitry Sergeevich Dunin
, 
Maxim V Tolstykh 2
Maxim V Tolstykh
, 
10.1016/j.mencom.2012.11.014
Published 2012-11-07
Communication , Volume 22, Issue 6, 320-322
4
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Birin K. P. et al. Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 320-322.
GOST all authors (up to 50) Copy
Birin K. P., Dunin D. S., Tolstykh M. V., Kotov V. Y. Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 320-322.
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TY - JOUR
DO - 10.1016/j.mencom.2012.11.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.014
TI - Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures
T2 - Mendeleev Communications
AU - Birin, Kirill Petrovich
AU - Dunin, Dmitry Sergeevich
AU - Tolstykh, Maxim V
AU - Kotov, Vitalii Yur'evich
PY - 2012
DA - 2012/11/07
PB - Mendeleev Communications
SP - 320-322
IS - 6
VL - 22
ER -
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@article{2012_Birin,
author = {Kirill Petrovich Birin and Dmitry Sergeevich Dunin and Maxim V Tolstykh and Vitalii Yur'evich Kotov},
title = {Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.014},
number = {6},
pages = {320--322},
doi = {10.1016/j.mencom.2012.11.014}
}
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Birin, Kirill Petrovich, et al. “Strong Negative Synergism of Ion Pair Extinction Coefficients in Chloroform–Acetone and Methylene Dichloride–Acetone Mixtures.” Mendeleev Communications, vol. 22, no. 6, Nov. 2012, pp. 320-322. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.014.

Abstract

The heteroselective preferential solvation of the iodides of N-heterocyclic aromatic cations in acetone–chloroalkane (chloroform and dichloromethane) binary mixtures results in not only a shift in the maxima of outer-sphere charge transfer absorption bands but also a considerable decrease in the molar extinction coefficients of ion pairs.

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