Home / Publications / HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones

HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones

Angelina Nikolaevna Kravchenko 1
Angelina Nikolaevna Kravchenko
, 
Galina Anatol'evna Gazieva 1
Galina Anatol'evna Gazieva
, 
Sergei Vitalyevich Vasilevskii 1
Sergei Vitalyevich Vasilevskii
, 
Pavel Alekseevich Belyakov 1
Pavel Alekseevich Belyakov
, 
10.1016/j.mencom.2012.11.006
Published 2012-11-07
Communication , Volume 22, Issue 6, 299-301
9
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Kravchenko A. N. et al. HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 299-301.
GOST all authors (up to 50) Copy
Kravchenko A. N., Gazieva G. A., Vasilevskii S. V., Belyakov P. A., Nelyubina Y. V. HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 299-301.
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TY - JOUR
DO - 10.1016/j.mencom.2012.11.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.006
TI - HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones
T2 - Mendeleev Communications
AU - Kravchenko, Angelina Nikolaevna
AU - Gazieva, Galina Anatol'evna
AU - Vasilevskii, Sergei Vitalyevich
AU - Belyakov, Pavel Alekseevich
AU - Nelyubina, Yulia Vladimirovna
PY - 2012
DA - 2012/11/07
PB - Mendeleev Communications
SP - 299-301
IS - 6
VL - 22
ER -
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@article{2012_Kravchenko,
author = {Angelina Nikolaevna Kravchenko and Galina Anatol'evna Gazieva and Sergei Vitalyevich Vasilevskii and Pavel Alekseevich Belyakov and Yulia Vladimirovna Nelyubina},
title = {HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.006},
number = {6},
pages = {299--301},
doi = {10.1016/j.mencom.2012.11.006}
}
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Kravchenko, Angelina Nikolaevna, et al. “HNO2-Assisted Triazine Cycle Contraction in 3-oxo-,3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenyl-perhydroimidazo[4,5-e][1,2,4]triazin-6-ones.” Mendeleev Communications, vol. 22, no. 6, Nov. 2012, pp. 299-301. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.006.

Abstract

Treatment of 3-oxo-, 3-thioxo- and 3-imino-5,7-dimethyl-4a,7a-diphenylperhydroimidazo[4,5-e][1,2,4]triazin-6-ones with NaNO2 in the presence of AcOH caused contraction of the perhydrotriazine cycle to the imidazolidine one. The products were transformed into glycolurils and their analogues.

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