Home / Publications / Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6

Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6

Natalia A Romanova 1
Natalia A Romanova
, 
Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
,  , 
Alexey Anatol'evich Goryunkov 1
Alexey Anatol'evich Goryunkov
,  , 
10.1016/j.mencom.2012.11.005
Published 2012-11-07
Communication , Volume 22, Issue 6, 297-298
13
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Romanova N. A. et al. Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6 // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 297-298.
GOST all authors (up to 50) Copy
Romanova N. A., Tamm N. B., Markov V. Y., Goryunkov A. A., Sidorov L. N., Troyanov S. I. Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6 // Mendeleev Communications. 2012. Vol. 22. No. 6. pp. 297-298.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2012.11.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.005
TI - Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6
T2 - Mendeleev Communications
AU - Romanova, Natalia A
AU - Tamm, Nadezhda Borisovna
AU - Markov, Vitaliy Yuryevich
AU - Goryunkov, Alexey Anatol'evich
AU - Sidorov, Lev Nikolaevich
AU - Troyanov, Sergey Igorevich
PY - 2012
DA - 2012/11/07
PB - Mendeleev Communications
SP - 297-298
IS - 6
VL - 22
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Romanova,
author = {Natalia A Romanova and Nadezhda Borisovna Tamm and Vitaliy Yuryevich Markov and Alexey Anatol'evich Goryunkov and Lev Nikolaevich Sidorov and Sergey Igorevich Troyanov},
title = {Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.005},
number = {6},
pages = {297--298},
doi = {10.1016/j.mencom.2012.11.005}
}
MLA
Cite this
MLA Copy
Romanova, Natalia A., et al. “Synthesis, X-ray Structure and Mass Spectrum of Cs-C60(CF3)6.” Mendeleev Communications, vol. 22, no. 6, Nov. 2012, pp. 297-298. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.11.005.

Abstract

Cs-C60(CF3)6 was synthesized by the reaction of S6-C60(CF3)12 with C60 at 530°C. Its molecular structure with skew-pentagonal- pyramidal addition pattern was elucidated by single crystal X-ray diffraction. Theoretical DFT calculations were performed to account for a high degree of fragmentation in negative-ion mass spectra.

References

1.
High-temperature and photochemical syntheses of C60 and C70 fullerene derivatives with linear perfluoroalkyl chains
Shustova N.B., Kareev I.E., Kuvychko I.V., Whitaker J.B., Lebedkin S.F., Popov A.A., Dunsch L., Chen Y., Seppelt K., Strauss S.H., Boltalina O.V.
Journal of Fluorine Chemistry, 2010
2.
Thermally Stable Perfluoroalkylfullerenes with the Skew-Pentagonal-Pyramid Pattern:  C60(C2F5)4O, C60(CF3)4O, and C60(CF3)6
Kareev I.E., Shustova N.B., Kuvychko I.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2006
3.
Synthesis, Structure, and Theoretical Study of Lower Trifluoromethyl Derivatives of [60]Fullerene
Dorozhkin E.I., Goryunkov A.A., Ioffe I.N., Avdoshenko S.M., Markov V.Y., Tamm N.B., Ignat'eva D.V., Sidorov L.N., Troyanov S.I.
European Journal of Organic Chemistry, 2007
4.
Mutig T., Kemnitz E., Troyanov S.I.
Mendeleev Communications, 2009
5.
Electrochemical, spectroscopic, and DFT study of C60(CF3)n frontier orbitals (n = 2-18): the link between double bonds in pentagons and reduction potentials.
Popov A.A., Kareev I.E., Shustova N.B., Stukalin E.B., Lebedkin S.F., Seppelt K., Strauss S.H., Boltalina O.V., Dunsch L.
Journal of the American Chemical Society, 2007
6.
Selective synthesis of a trifluoromethylated fullerene and the crystal structure of C60(CF3)12.
Troyanov S.I., Dimitrov A., Kemnitz E.
Angewandte Chemie - International Edition, 2006
7.
Preparation and 13C NMR spectroscopic characterisation of C60Cl6
Birkett P.R., Avent A.G., Darwish A.D., Kroto H.W., Taylor R., Walton D.R.
Journal of the Chemical Society Chemical Communications, 1993
9.
Preparation and characterization of C60Br6 and C60Br8
Birkett P.R., Hitchcock P.B., Kroto H.W., Taylor R., Walton D.R.
Nature, 1992
10.
The First X-ray Crystal Structures of Halogenated [70]Fullerene: C70Br10 and C70Br10⋅3 Br2
Troyanov S.I., Popov A.A., Denisenko N.I., Boltalina O.V., Sidorov L.N., Kemnitz E.
Angewandte Chemie - International Edition, 2003
11.
10.1016/j.mencom.2012.11.005_bib0055
Al-Matar
J. Chem. Soc., Perkin Trans. 2, 2002
12.
Mass spectrometric studies of trifluoromethylated fullerenes
Markov V.Y., Aleshina V.E., Borschevskiy A.Y., Khatymov R.V., Tuktarov R.F., Pogulay A.V., Maximov A.L., Kardashev S.V., Ioffe I.N., Avdoshenko S.M., Dorozhkin E.I., Goryunkov A.A., Ignat’eva D.V., Gruzinskaya N.I., Sidorov L.N., et. al.
International Journal of Mass Spectrometry, 2006
14.
Generalized Gradient Approximation Made Simple
Perdew J.P., Burke K., Ernzerhof M.
Physical Review Letters, 1996
15.
Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives
Avdoshenko S.M., Ioffe I.N., Sidorov L.N.
Journal of Physical Chemistry A, 2009