Home / Publications / Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions

Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions

Vera Leonidovna Sigacheva 1
Vera Leonidovna Sigacheva
, 
Vladimir Alekseevich Kokorekin 1
Vladimir Alekseevich Kokorekin
, 
Yurii Andreevich Strelenko 1
Yurii Andreevich Strelenko
,  , 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2012.09.015
Published 2012-09-17
Communication , Volume 22, Issue 5, 270-272
16
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Sigacheva V. L. et al. Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions // Mendeleev Communications. 2012. Vol. 22. No. 5. pp. 270-272.
GOST all authors (up to 50) Copy
Sigacheva V. L., Kokorekin V. A., Strelenko Y. A., Neverov S. V., Petrosyan V. A. Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions // Mendeleev Communications. 2012. Vol. 22. No. 5. pp. 270-272.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2012.09.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.015
TI - Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions
T2 - Mendeleev Communications
AU - Sigacheva, Vera Leonidovna
AU - Kokorekin, Vladimir Alekseevich
AU - Strelenko, Yurii Andreevich
AU - Neverov, Sergey Vladimirovich
AU - Petrosyan, Vladimir Anushavanovich
PY - 2012
DA - 2012/09/17
PB - Mendeleev Communications
SP - 270-272
IS - 5
VL - 22
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Sigacheva,
author = {Vera Leonidovna Sigacheva and Vladimir Alekseevich Kokorekin and Yurii Andreevich Strelenko and Sergey Vladimirovich Neverov and Vladimir Anushavanovich Petrosyan},
title = {Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.015},
number = {5},
pages = {270--272},
doi = {10.1016/j.mencom.2012.09.015}
}
MLA
Cite this
MLA Copy
Sigacheva, Vera Leonidovna, et al. “Electrochemical Azolation of N-substituted Pyrroles: A New Case in SNH(An) Reactions.” Mendeleev Communications, vol. 22, no. 5, Sep. 2012, pp. 270-272. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.015.

Abstract

Potentiostatic electrolysis (divided cell, anode compartment) of 1-methyl- and 1-phenylpyrroles in the presence of sodium 4-nitro-pyrazolate and sodium 3-nitropyrazolate in MeCN/MeOH gave the corresponding 2-(azol-1-yl)pyrroles in 20–43% current and substance yields.

References

1.
10.1016/j.mencom.2012.09.015_bib0005
Yoshida
The Role of Cation Radicals as Synthetic Intermediates, 1984
2.
Reactions of some arenes and pyrazoles in MeCN under conditions of undivided-cell electrolysis
Chauzov V.A., Parchinsky V.Z., Sinelshchikova E.V., Petrosyan V.A.
Russian Chemical Bulletin, 2001
5.
Anodic azolation of 1,2- and 1,3-dimethoxybenzenes
Petrosyan V.A., Burasov A.V.
Russian Chemical Bulletin, 2010
6.
Oral Azole Drugs as Systemic Antifungal Therapy
Wood A.J., Como J.A., Dismukes W.E.
New England Journal of Medicine, 1994
8.
An Improved and Scalable Process for Celecoxib: A Selective Cyclooxygenase-2 Inhibitor
Reddy A.R., Sampath A., Goverdhan G., Yakambaram B., Mukkanti K., Reddy P.P.
Organic Process Research and Development, 2008
9.
R. A. Newberry, Brit. Pat. 1,373,212.(Chem. Abstr., 1975, 82, 72987t).
12.
Spectroelectrochemical study of polypyrrole films
Genies E.M., Bidan G., Diaz A.F.
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1983
14.
Nucleophilic Substitution of Hydrogen in Heteroaromatics
Chupakhin O.N., Charushin V.N., van der Pias H.C.
1994
17.
ChemAxon.(http://www.chemaxon.com).