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Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative

Elena Aleksandrovna Alekseeva 1
Elena Aleksandrovna Alekseeva
, 
Alexandr P Luk'yanenko 1
Alexandr P Luk'yanenko
, 
Andrei Ivanovich Gren 1
Andrei Ivanovich Gren
1 A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
10.1016/j.mencom.2012.09.012
Published 2012-09-17
Communication , Volume 22, Issue 5, 263-264
4
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Alekseeva E. A., Luk'yanenko A. P., Gren A. I. Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative // Mendeleev Communications. 2012. Vol. 22. No. 5. pp. 263-264.
GOST all authors (up to 50) Copy
Alekseeva E. A., Luk'yanenko A. P., Gren A. I. Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative // Mendeleev Communications. 2012. Vol. 22. No. 5. pp. 263-264.
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TY - JOUR
DO - 10.1016/j.mencom.2012.09.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.012
TI - Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative
T2 - Mendeleev Communications
AU - Alekseeva, Elena Aleksandrovna
AU - Luk'yanenko, Alexandr P
AU - Gren, Andrei Ivanovich
PY - 2012
DA - 2012/09/17
PB - Mendeleev Communications
SP - 263-264
IS - 5
VL - 22
ER -
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@article{2012_Alekseeva,
author = {Elena Aleksandrovna Alekseeva and Alexandr P Luk'yanenko and Andrei Ivanovich Gren},
title = {Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.012},
number = {5},
pages = {263--264},
doi = {10.1016/j.mencom.2012.09.012}
}
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Alekseeva, Elena Aleksandrovna, et al. “Synthesis and Complexation properties of N,N’-bis(calix[4]Arenoxyacetyl)Hydrazine Derivative.” Mendeleev Communications, vol. 22, no. 5, Sep. 2012, pp. 263-264. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.09.012.

Abstract

Heating of p-tert-butylcalix[4]arene bearing acethydrazide moiety at the lower rim in MeCN or PriOH (EtOH) affords the corresponding N,N’-bis(calix[4]arenoxyacetyl)hydrazine derivative. The hydrazinolysis of mono(methoxycarbonylmethoxy)-p-tert-butylcalix[4]-arene in benzene or refluxing biscalixarene hydrazide in benzene in the presence of hydrazine hydrate produces the mixture of 1,2- and 1,3-(N,N’-diacetylhydrazine)-p-tert-butylcalix[4]arenes.

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