Home / Publications / Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System

Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System

Ayse Bakar 1
Ayse Bakar
, 
Victor Vladimirovich De 2
Victor Vladimirovich De
, 
Alexey Alexandrovich Zezin 2, 3
Alexey Alexandrovich Zezin
, 
Sergey Savel'evich Abramchuk 2
Sergey Savel'evich Abramchuk
, 
Olgun Guven 1
Olgun Guven
, 
Vladimir Isaevich Feldman 2
Vladimir Isaevich Feldman
10.1016/j.mencom.2012.06.014
Published 2012-06-13
Communication , Volume 22, Issue 4, 211-212
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Bakar A. et al. Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 211-212.
GOST all authors (up to 50) Copy
Bakar A., De V. V., Zezin A. A., Abramchuk S. S., Guven O., Feldman V. I. Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 211-212.
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TY - JOUR
DO - 10.1016/j.mencom.2012.06.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.014
TI - Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System
T2 - Mendeleev Communications
AU - Bakar, Ayse
AU - De, Victor Vladimirovich
AU - Zezin, Alexey Alexandrovich
AU - Abramchuk, Sergey Savel'evich
AU - Guven, Olgun
AU - Feldman, Vladimir Isaevich
PY - 2012
DA - 2012/06/13
PB - Mendeleev Communications
SP - 211-212
IS - 4
VL - 22
ER -
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@article{2012_Bakar,
author = {Ayse Bakar and Victor Vladimirovich De and Alexey Alexandrovich Zezin and Sergey Savel'evich Abramchuk and Olgun Guven and Vladimir Isaevich Feldman},
title = {Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.014},
number = {4},
pages = {211--212},
doi = {10.1016/j.mencom.2012.06.014}
}
MLA
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Bakar, Ayse, et al. “Spatial Organization of a Metal–Polymer Nanocomposite Obtained by the Radiation-Induced Reduction of Copper Ions in the Poly(Allylamine)–Poly(Acrylic Acid)–Cu2+ System.” Mendeleev Communications, vol. 22, no. 4, Jun. 2012, pp. 211-212. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.014.

Keywords

copper nanoparticles
metal-polymer nanocomposites
radiation-chemical reduction
two-level structure

Abstract

The X-ray-induced reduction of Cu2+ ions in aqueous–alcoholic suspensions containing poly(allylamine) and poly(acrylic acid) leads to a specific microheterogeneous structure with microdomains (100–200 nm) enriched by small copper nanoparticles (2 to 4 nm), which are dispersed in a continuous matrix.

References

1.
Microaggregates of non-noble metals and bimetallic alloys prepared by radiation-induced reduction
Marignier J.L., Belloni J., Delcourt M.O., Chevalier J.P.
Nature, 1985
2.
10.1016/j.mencom.2012.06.014_bib0010
Ershov
Izv. Akad. Nauk, Ser. Khim., 1994
3.
Dose Rate Effect on Bimetallic Gold−Palladium Cluster Structure
Remita H., Etcheberry A., Belloni J.
Journal of Physical Chemistry B, 2002
4.
Radiation induced synthesis and characterization of copper nanoparticles
Joshi S.S., Patil S.F., Iyer V., Mahumuni S.
Nanostructured Materials, 1998
5.
Prospects and challenges in application of gamma, electron and ion beams in processing of nanomaterials
Chmielewski A.G., Chmielewska D.K., Michalik J., Sampa M.H.
Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 2007
6.
The peculiarities of formation of the metal nanoparticles in irradiated polymer metal complexes
Zezin A.A., Feldman V.I., Shmakova N.A., Valueva S.P., Ivanchenko V.K., Nikanorova N.I.
Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms, 2007
7.
10.1016/j.mencom.2012.06.014_bib0035
Ershov
Kolloidn. Zh., 2009
8.
From triple interpolyelectrolyte-metal complexes to polymer-metal nanocomposites
Zezin A.B., Rogacheva V.B., Feldman V.I., Afanasiev P., Zezin A.A.
Advances in Colloid and Interface Science, 2010
9.
The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation
Zezin A.A., Feldman V.I., Zezina E.A., Belopushkin S.I., Tsybina E.V., Abramchuk S.S., Zezin S.B.
High Energy Chemistry, 2011
10.
10.1016/j.mencom.2012.06.014_bib0050
Zezin
Vysokomol. Soedin., 2011
12.
Nanostructured polymeric systems as nanoreactors for nanoparticle formation
Bronstein L.M., Sidorov S.N., Valetsky P.M.
Russian Chemical Reviews, 2004
13.
Polymer Microgels:  Reactors for Semiconductor, Metal, and Magnetic Nanoparticles
Zhang J., Xu S., Kumacheva E.
Journal of the American Chemical Society, 2004