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[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+

Èduard Èduardovich Karslyan 1
Èduard Èduardovich Karslyan
Andrew I Konovalov 1
Andrew I Konovalov
Alexandra Olegovna Borissova 1
Alexandra Olegovna Borissova
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
Published 2012-06-13
CommunicationVolume 22, Issue 4, 189-191
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Karslyan È. È. et al. [2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+ // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 189-191.
GOST all authors (up to 50) Copy
Karslyan È. È., Konovalov A. I., Borissova A. O., Petrovskii P. V., Kudinov A. R. [2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+ // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 189-191.
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TY - JOUR
DO - 10.1016/j.mencom.2012.06.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.005
TI - [2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+
T2 - Mendeleev Communications
AU - Karslyan, Èduard Èduardovich
AU - Konovalov, Andrew I
AU - Borissova, Alexandra Olegovna
AU - Petrovskii, Pavel Vasil'evich
AU - Kudinov, Alexander Rudolfovich
PY - 2012
DA - 2012/06/13
PB - Mendeleev Communications
SP - 189-191
IS - 4
VL - 22
ER -
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@article{2012_Karslyan,
author = {Èduard Èduardovich Karslyan and Andrew I Konovalov and Alexandra Olegovna Borissova and Pavel Vasil'evich Petrovskii and Alexander Rudolfovich Kudinov},
title = {[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.005},
number = {4},
pages = {189--191},
doi = {10.1016/j.mencom.2012.06.005}
}
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Karslyan, Èduard Èduardovich, et al. “[2 + 2] Photodimerization of the acenaphthylene ruthenium complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+.” Mendeleev Communications, vol. 22, no. 4, Jun. 2012, pp. 189-191. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.005.

Abstract

The [2+2] photodimerization of the complex [(C5Me4CH2OMe)Ru(η6-C12H8)]+ under visible-light irradiation leads to a mixture of the head-to-head heptacyclene products [(μ-η6: η6-C24H16)Ru2(C5Me4CH2OMe)2]2+ (syn- and anti-) with the predominant formation of the syn-isomer; the structures of both isomers were established by X-ray diffraction analysis.

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