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Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Natalia Alekseevna Belogorlova 1
Natalia Alekseevna Belogorlova
, 
Anastasiya O Korocheva 1
Anastasiya O Korocheva
, 
Olga Nikolaevna Kazheva 2
Olga Nikolaevna Kazheva
, 
Grigorii Grigor'evich Alexandrov 3
Grigorii Grigor'evich Alexandrov
, 
Oleg Anatol'evich Dyachenko 2
Oleg Anatol'evich Dyachenko
10.1016/j.mencom.2012.06.004
Published 2012-06-13
Communication , Volume 22, Issue 4, 187-188
26
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Trofimov B. A. et al. Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 187-188.
GOST all authors (up to 50) Copy
Trofimov B. A., Gusarova N. K., Artem’ev A. V., Malysheva S. F., Belogorlova N. A., Korocheva A. O., Kazheva O. N., Alexandrov G. G., Dyachenko O. A. Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride // Mendeleev Communications. 2012. Vol. 22. No. 4. pp. 187-188.
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TY - JOUR
DO - 10.1016/j.mencom.2012.06.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.004
TI - Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Gusarova, Nina Kuzminichna
AU - Artem’ev, Alexandr Viktorovich
AU - Malysheva, Svetlana Filippovna
AU - Belogorlova, Natalia Alekseevna
AU - Korocheva, Anastasiya O
AU - Kazheva, Olga Nikolaevna
AU - Alexandrov, Grigorii Grigor'evich
AU - Dyachenko, Oleg Anatol'evich
PY - 2012
DA - 2012/06/13
PB - Mendeleev Communications
SP - 187-188
IS - 4
VL - 22
ER -
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@article{2012_Trofimov,
author = {Boris Aleksandrovich Trofimov and Nina Kuzminichna Gusarova and Alexandr Viktorovich Artem’ev and Svetlana Filippovna Malysheva and Natalia Alekseevna Belogorlova and Anastasiya O Korocheva and Olga Nikolaevna Kazheva and Grigorii Grigor'evich Alexandrov and Oleg Anatol'evich Dyachenko},
title = {Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.004},
number = {4},
pages = {187--188},
doi = {10.1016/j.mencom.2012.06.004}
}
MLA
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Trofimov, Boris Aleksandrovich, et al. “Tris(2-pyridyl)phosphine: a straightforward microwave-assisted synthesis from 2-bromopyridine and red phosphorus and coordination with cobalt(ii) dichloride.” Mendeleev Communications, vol. 22, no. 4, Jun. 2012, pp. 187-188. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.06.004.

Abstract

Microwave irradiation of 2-bromopyridine with red phosphorus in the superbasic KOH/DMSO (H2O) suspension affords tris(2-pyridyl)phosphine in 53% yield; two molecules of tris(2-pyridyl)phosphine coordinate with CoCl2 by their six nitrogen atoms only to form [Co(2-Py3P)2]Cl2⋅8H2O complex having two phosphorus atoms beyond the coordination sphere.

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