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The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide

Vasiliy Georgievich Shtamburg 1, 2
Vasiliy Georgievich Shtamburg
, 
Alexander Valerievich Tsygankov 3
Alexander Valerievich Tsygankov
, 
Oleg Valer'ievich Shishkin 4
Oleg Valer'ievich Shishkin
, 
Roman Igorevich Zubatyuk 4
Roman Igorevich Zubatyuk
, 
Boris V Uspensky 2
Boris V Uspensky
, 
Victor Vasil'evich Shtamburg 2
Victor Vasil'evich Shtamburg
, 
Alexander Vladimirovich Mazepa 5
Alexander Vladimirovich Mazepa
, 
Remir Grigorevich Kostyanovsky 6
Remir Grigorevich Kostyanovsky
1 Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
2 Department of Chemistry, National Technical University 'Kharkov Polytechnic Institute', Kharkov, Ukraine
3 State Flight Academy of Ukraine, Kirovograd, Ukraine
4 STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
5 A.V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
10.1016/j.mencom.2012.05.019
Published 2012-04-27
Communication , Volume 22, Issue 3, 164-166
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Shtamburg V. G. et al. The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide // Mendeleev Communications. 2012. Vol. 22. No. 3. pp. 164-166.
GOST all authors (up to 50) Copy
Shtamburg V. G., Tsygankov A. V., Shishkin O. V., Zubatyuk R. I., Uspensky B. V., Shtamburg V. V., Mazepa A. V., Kostyanovsky R. G. The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide // Mendeleev Communications. 2012. Vol. 22. No. 3. pp. 164-166.
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TY - JOUR
DO - 10.1016/j.mencom.2012.05.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.019
TI - The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide
T2 - Mendeleev Communications
AU - Shtamburg, Vasiliy Georgievich
AU - Tsygankov, Alexander Valerievich
AU - Shishkin, Oleg Valer'ievich
AU - Zubatyuk, Roman Igorevich
AU - Uspensky, Boris V
AU - Shtamburg, Victor Vasil'evich
AU - Mazepa, Alexander Vladimirovich
AU - Kostyanovsky, Remir Grigorevich
PY - 2012
DA - 2012/04/27
PB - Mendeleev Communications
SP - 164-166
IS - 3
VL - 22
ER -
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@article{2012_Shtamburg,
author = {Vasiliy Georgievich Shtamburg and Alexander Valerievich Tsygankov and Oleg Valer'ievich Shishkin and Roman Igorevich Zubatyuk and Boris V Uspensky and Victor Vasil'evich Shtamburg and Alexander Vladimirovich Mazepa and Remir Grigorevich Kostyanovsky},
title = {The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.019},
number = {3},
pages = {164--166},
doi = {10.1016/j.mencom.2012.05.019}
}
MLA
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Shtamburg, Vasiliy Georgievich, et al. “The properties and structure of N-chloro-N-methoxy-4-nitrobenzamide.” Mendeleev Communications, vol. 22, no. 3, Apr. 2012, pp. 164-166. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.019.

Abstract

The XRD study of N-chloro-N-methoxy-4-nitrobenzamide revealed the high pyramidality degree of its amide nitrogen atom in O–N–Cl moiety. N-Chloro-N-methoxy-4-nitrobenzamide reacts with AcONa in MeCN selectively forming N-acetoxy-N-methoxy-4-nitrobenzamide, whereas its methanolysis in the presence of AcONa yields N,N’-bis(4-nitrobenzoyl)-N,N’-dimethoxyhydrazine.

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