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Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant

Ivan Mikhailovich Kumanyaev 1
Ivan Mikhailovich Kumanyaev
, 
Margarita Aleksandrovna Lapitskaya 1
Margarita Aleksandrovna Lapitskaya
, 
Ljudmila Leonidovna Vasiljeva 1
Ljudmila Leonidovna Vasiljeva
, 
Kazimir Konstantinovich Pivnitsky 1
Kazimir Konstantinovich Pivnitsky
10.1016/j.mencom.2012.05.004
Published 2012-04-27
Communication , Volume 22, Issue 3, 129-131
9
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Kumanyaev I. M. et al. Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant // Mendeleev Communications. 2012. Vol. 22. No. 3. pp. 129-131.
GOST all authors (up to 50) Copy
Kumanyaev I. M., Lapitskaya M. A., Vasiljeva L. L., Pivnitsky K. K. Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant // Mendeleev Communications. 2012. Vol. 22. No. 3. pp. 129-131.
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TY - JOUR
DO - 10.1016/j.mencom.2012.05.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.004
TI - Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant
T2 - Mendeleev Communications
AU - Kumanyaev, Ivan Mikhailovich
AU - Lapitskaya, Margarita Aleksandrovna
AU - Vasiljeva, Ljudmila Leonidovna
AU - Pivnitsky, Kazimir Konstantinovich
PY - 2012
DA - 2012/04/27
PB - Mendeleev Communications
SP - 129-131
IS - 3
VL - 22
ER -
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@article{2012_Kumanyaev,
author = {Ivan Mikhailovich Kumanyaev and Margarita Aleksandrovna Lapitskaya and Ljudmila Leonidovna Vasiljeva and Kazimir Konstantinovich Pivnitsky},
title = {Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.004},
number = {3},
pages = {129--131},
doi = {10.1016/j.mencom.2012.05.004}
}
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Kumanyaev, Ivan Mikhailovich, et al. “Pyridinium o-iodoxybenzoate as a Safe form of a Famous Oxidant.” Mendeleev Communications, vol. 22, no. 3, Apr. 2012, pp. 129-131. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.05.004.

Abstract

The stable pyridinium salt of o-iodoxybenzoic acid (PIBX) that is easy to obtain can serve as a convenient substitute of IBX as an oxidant. PIBX is safer, has neutral properties behaves as an equivalent to IBX in the oxidation of alcohols to ketones or aldehydes in polar solvents (DMF, DMSO), and provides higher oxidation rate in THF due to better solubility.

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