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Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione

Nadezhda Vasilievna Vasilieva 1
Nadezhda Vasilievna Vasilieva
, 
Irina Gennad'evna Irtegova 1
Irina Gennad'evna Irtegova
, 
Vladimir Alekseevich Loskutov 1
Vladimir Alekseevich Loskutov
, 
Leonid Anatol'evich Shundrin 1
Leonid Anatol'evich Shundrin
10.1016/j.mencom.2012.03.021
Published 2012-02-27
Communication , Volume 22, Issue 2, 111-113
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Vasilieva N. V. et al. Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 111-113.
GOST all authors (up to 50) Copy
Vasilieva N. V., Irtegova I. G., Loskutov V. A., Shundrin L. A. Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 111-113.
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TY - JOUR
DO - 10.1016/j.mencom.2012.03.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.021
TI - Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione
T2 - Mendeleev Communications
AU - Vasilieva, Nadezhda Vasilievna
AU - Irtegova, Irina Gennad'evna
AU - Loskutov, Vladimir Alekseevich
AU - Shundrin, Leonid Anatol'evich
PY - 2012
DA - 2012/02/27
PB - Mendeleev Communications
SP - 111-113
IS - 2
VL - 22
ER -
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@article{2012_Vasilieva,
author = {Nadezhda Vasilievna Vasilieva and Irina Gennad'evna Irtegova and Vladimir Alekseevich Loskutov and Leonid Anatol'evich Shundrin},
title = {Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.021},
number = {2},
pages = {111--113},
doi = {10.1016/j.mencom.2012.03.021}
}
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Vasilieva, Nadezhda Vasilievna, et al. “Electrochemical reduction and radical anions of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione.” Mendeleev Communications, vol. 22, no. 2, Feb. 2012, pp. 111-113. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.021.

Keywords

cyclic voltammetry
electrochemical reduction
radical anions
thioxanthenes

Abstract

The electrochemical reduction of benzo[b]thioxanthene-6,11,12-trione and thioxanthene-1,4,9-trione in DMSO, MeCN and HMPA is an EE process, which is characterized by two separate one electron reversible peaks on cyclic voltammograms, first peak retains reversibility in DMSO–H2O mixtures, corresponding radical anions were obtained by one electron reduction of the above compounds and characterized by EPR and DFT calculations at the (U)B3LYP/6-31+G* level of theory.

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