Home / Publications / Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction

Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction

Victor Ivanovich Markov ¹

Victor Ivanovich Markov

Oleg Konstantinovich Farat ¹

Oleg Konstantinovich Farat

Svetlana Anatol'evna Varenichenko ¹

Svetlana Anatol'evna Varenichenko

Ekaterina Vladimirovna Velikaya ¹

Ekaterina Vladimirovna Velikaya

¹ Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine

10.1016/j.mencom.2012.03.017

Copy DOI

Published 2012-02-27

Communication , Volume 22, Issue 2, 101-102

View PDF

Supporting information

Cite this

GOST

Cite this

GOST Copy

Markov V. I. et al. Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 101-102.

GOST all authors (up to 50) Copy

Markov V. I., Farat O. K., Varenichenko S. A., Velikaya E. V. Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 101-102.

RIS

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2012.03.017

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.017

TI - Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction

T2 - Mendeleev Communications

AU - Markov, Victor Ivanovich

AU - Farat, Oleg Konstantinovich

AU - Varenichenko, Svetlana Anatol'evna

AU - Velikaya, Ekaterina Vladimirovna

PY - 2012

DA - 2012/02/27

PB - Mendeleev Communications

SP - 101-102

IS - 2

VL - 22

ER -

BibTex

Cite this

BibTex (up to 50 authors) Copy

@article{2012_Markov,

author = {Victor Ivanovich Markov and Oleg Konstantinovich Farat and Svetlana Anatol'evna Varenichenko and Ekaterina Vladimirovna Velikaya},

title = {Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction},

journal = {Mendeleev Communications},

year = {2012},

volume = {22},

publisher = {Mendeleev Communications},

month = {Feb},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.017},

number = {2},

pages = {101--102},

doi = {10.1016/j.mencom.2012.03.017}

}

MLA

Cite this

MLA Copy

Markov, Victor Ivanovich, et al. “Rearrangement of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’(3’H)-one during the Vilsmeier reaction.” Mendeleev Communications, vol. 22, no. 2, Feb. 2012, pp. 101-102. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.017.

Abstract

Treatment of 5’,6’,7’,8’-tetrahydro-1’H-spiro(cyclohexane-1,2’-quinazolin)-4’ (3’H)-one with POCl3 and DMF gives a mixture of 1,2,3,4,5,6,7,8-octahydroacridine-4-carbonitrile and 4,5-diformyl-2,3,6,7,8,10-hexahydroacridine-8a(1H)-carbonitrile, both products resulting from cascade transformations of the primary Vilsmeier intermediates.

References

10.1021/jo01060a017

Novel Condensation of Cyclohexanone with Urea

McKAY A.F., TARLTON E.J., PODESVA C.

Journal of Organic Chemistry, 1961

10.1021/jo01068a025

The Reaction of Urea with Cyclic 1,3-Dicarbonyl and Other Active Hydrogen Compounds

SCARBOROUGH H.C., GOULD W.A.

Journal of Organic Chemistry, 1961

10.1007/BF00911421

�ber das Tetrahydrospiro [cyclohexan-1,2?(1?H)-chinazolin]-4?(3?H)-on

Zigeuner G., G�bitz G.

Monatshefte fur Chemie, 1970

A. V. Upadysheva, N.D. Grigor’eva and A. P. Znamenskaya, Khim. Geterotsikl. Soedin., 1977, 1549.[Chem. Heterocycl. Compd. (Engl. Transl.), 1977, 13, 1240].

A. V. Upadysheva, N.D. Grigor’eva, Yu. S. Ryabokobylko and A. P. Znamenskaya, Khim. Geterotsikl. Soedin., 1983, 107.[Chem. Heterocycl. Compd. (Engl. Transl.), 1983, 19, 95].