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Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Elena V Skital’tseva 1
Elena V Skital’tseva
, 
Ivan A. Bidusenko 1
Ivan A. Bidusenko
, 
Nadezhda Victorovna Zorina 1
Nadezhda Victorovna Zorina
, 
Albina Ivanovna Mikhaleva 1
Albina Ivanovna Mikhaleva
10.1016/j.mencom.2012.03.002
Published 2012-02-27
Communication , Volume 22, Issue 2, 62-63
8
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Trofimov B. A. et al. Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 62-63.
GOST all authors (up to 50) Copy
Trofimov B. A., Schmidt E. Y., Skital’tseva E. V., Bidusenko I. A., Zorina N. V., Mikhaleva A. I. Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples // Mendeleev Communications. 2012. Vol. 22. No. 2. pp. 62-63.
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TY - JOUR
DO - 10.1016/j.mencom.2012.03.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.002
TI - Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Schmidt, Elena Yur'evna
AU - Skital’tseva, Elena V
AU - Bidusenko, Ivan A.
AU - Zorina, Nadezhda Victorovna
AU - Mikhaleva, Albina Ivanovna
PY - 2012
DA - 2012/02/27
PB - Mendeleev Communications
SP - 62-63
IS - 2
VL - 22
ER -
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@article{2012_Trofimov,
author = {Boris Aleksandrovich Trofimov and Elena Yur'evna Schmidt and Elena V Skital’tseva and Ivan A. Bidusenko and Nadezhda Victorovna Zorina and Albina Ivanovna Mikhaleva},
title = {Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples},
journal = {Mendeleev Communications},
year = {2012},
volume = {22},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.002},
number = {2},
pages = {62--63},
doi = {10.1016/j.mencom.2012.03.002}
}
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Trofimov, Boris Aleksandrovich, et al. “Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples.” Mendeleev Communications, vol. 22, no. 2, Feb. 2012, pp. 62-63. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.03.002.

Abstract

1-Ethynylcyclohexanol and 1-ethynylcycloheptanol are O-vinylated with acetylene in KOH/DMSO superbase system (90°C, autoclave, initial acetylene pressure of 14 atm, 1h) to afford the corresponding vinyl ethers in 40 and 34% yields, respectively.

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