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Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions

Andrei Alexandrovich Vasil'ev 1
Andrei Alexandrovich Vasil'ev
, 
Sergey Evgen'evich Lyubimov 2
Sergey Evgen'evich Lyubimov
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
, 
Vadim Alexandrovich Davankov 2
Vadim Alexandrovich Davankov
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2012.01.015
Published 2011-12-29
Communication , Volume 22, Issue 1, 39-40
7
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Vasil'ev A. A. et al. Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 39-40.
GOST all authors (up to 50) Copy
Vasil'ev A. A., Lyubimov S. E., Serebryakov E. P., Davankov V. A., Zlotin S. G. Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 39-40.
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TY - JOUR
DO - 10.1016/j.mencom.2012.01.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.015
TI - Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions
T2 - Mendeleev Communications
AU - Vasil'ev, Andrei Alexandrovich
AU - Lyubimov, Sergey Evgen'evich
AU - Serebryakov, Edward Prokof'evich
AU - Davankov, Vadim Alexandrovich
AU - Zlotin, Sergei Grigorievich
PY - 2011
DA - 2011/12/29
PB - Mendeleev Communications
SP - 39-40
IS - 1
VL - 22
ER -
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@article{2011_Vasil'ev,
author = {Andrei Alexandrovich Vasil'ev and Sergey Evgen'evich Lyubimov and Edward Prokof'evich Serebryakov and Vadim Alexandrovich Davankov and Sergei Grigorievich Zlotin},
title = {Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions},
journal = {Mendeleev Communications},
year = {2011},
volume = {22},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.015},
number = {1},
pages = {39--40},
doi = {10.1016/j.mencom.2012.01.015}
}
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Vasil'ev, Andrei Alexandrovich, et al. “Asymmetric Tsuji–Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions.” Mendeleev Communications, vol. 22, no. 1, Dec. 2011, pp. 39-40. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.015.

Abstract

P*-Chiral diamidophosphite ligand-assisted Pd-catalyzed Tsuji–Trost reaction between dimethyl malonate and prochiral 3-acetoxy-1,3-diphenylpropene in organic solvents using potassium carbonate as the base affords the substitution product in quantitative yields and with enantioselectivities up to 99% ee.

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