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Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine

Alexandr Viktorovich Artem’ev 1
Alexandr Viktorovich Artem’ev
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Boris Genad'evch Sukhov 1
Boris Genad'evch Sukhov
, 
Natalia Alekseevna Belogorlova 1
Natalia Alekseevna Belogorlova
, 
Yuriy Vasil'evich Gatilov 2
Yuriy Vasil'evich Gatilov
, 
Victor Il'ich Mamatyuk 2
Victor Il'ich Mamatyuk
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
10.1016/j.mencom.2012.01.006
Published 2011-12-29
Communication , Volume 22, Issue 1, 18-20
12
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Artem’ev A. V. et al. Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 18-20.
GOST all authors (up to 50) Copy
Artem’ev A. V., Malysheva S. F., Sukhov B. G., Belogorlova N. A., Gatilov Y. V., Mamatyuk V. I., Gusarova N. K. Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 18-20.
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TY - JOUR
DO - 10.1016/j.mencom.2012.01.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.006
TI - Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine
T2 - Mendeleev Communications
AU - Artem’ev, Alexandr Viktorovich
AU - Malysheva, Svetlana Filippovna
AU - Sukhov, Boris Genad'evch
AU - Belogorlova, Natalia Alekseevna
AU - Gatilov, Yuriy Vasil'evich
AU - Mamatyuk, Victor Il'ich
AU - Gusarova, Nina Kuzminichna
PY - 2011
DA - 2011/12/29
PB - Mendeleev Communications
SP - 18-20
IS - 1
VL - 22
ER -
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@article{2011_Artem’ev,
author = {Alexandr Viktorovich Artem’ev and Svetlana Filippovna Malysheva and Boris Genad'evch Sukhov and Natalia Alekseevna Belogorlova and Yuriy Vasil'evich Gatilov and Victor Il'ich Mamatyuk and Nina Kuzminichna Gusarova},
title = {Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine},
journal = {Mendeleev Communications},
year = {2011},
volume = {22},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.006},
number = {1},
pages = {18--20},
doi = {10.1016/j.mencom.2012.01.006}
}
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Artem’ev, Alexandr Viktorovich, et al. “Unexpected redox reaction of alkali metal diselenophosphinates with elemental iodine.” Mendeleev Communications, vol. 22, no. 1, Dec. 2011, pp. 18-20. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.006.

Abstract

Redox reaction between alkali metal diselenophosphinates R2P(Se)SeM (M = Na, K) and elemental iodine in a 2:1 molar ratio (1,4-dioxane, room temperature, 2min) gives bis(diorganylselenophosphoryl)selenides [R2P(Se)]2Se and bis(diorganylselenophosphoryl) triselenides [R2P(Se)]2Se3 in 87–90% total yields.

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