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The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3

Alexander Sergeyevich Romanov 1
Alexander Sergeyevich Romanov
, 
Dmitry Victorovich Muratov 1
Dmitry Victorovich Muratov
, 
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
, 
Walter Siebert 2
Walter Siebert
, 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
2 Fakultaet fuer Chemie, Institut fuer Anorganische Chemie, Ruprecht-Karls-Universitaet zu Heidelberg, Germany
10.1016/j.mencom.2012.01.004
Published 2011-12-29
Communication , Volume 22, Issue 1, 13-14
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Romanov A. S. et al. The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3 // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 13-14.
GOST all authors (up to 50) Copy
Romanov A. S., Muratov D. V., Petrovskii P. V., Siebert W., Kudinov A. R. The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3 // Mendeleev Communications. 2011. Vol. 22. No. 1. pp. 13-14.
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TY - JOUR
DO - 10.1016/j.mencom.2012.01.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.004
TI - The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3
T2 - Mendeleev Communications
AU - Romanov, Alexander Sergeyevich
AU - Muratov, Dmitry Victorovich
AU - Petrovskii, Pavel Vasil'evich
AU - Siebert, Walter
AU - Kudinov, Alexander Rudolfovich
PY - 2011
DA - 2011/12/29
PB - Mendeleev Communications
SP - 13-14
IS - 1
VL - 22
ER -
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@article{2011_Romanov,
author = {Alexander Sergeyevich Romanov and Dmitry Victorovich Muratov and Pavel Vasil'evich Petrovskii and Walter Siebert and Alexander Rudolfovich Kudinov},
title = {The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3},
journal = {Mendeleev Communications},
year = {2011},
volume = {22},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.004},
number = {1},
pages = {13--14},
doi = {10.1016/j.mencom.2012.01.004}
}
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Romanov, Alexander Sergeyevich, et al. “The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3.” Mendeleev Communications, vol. 22, no. 1, Dec. 2011, pp. 13-14. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2012.01.004.

Abstract

The μ-diborolyl triple-decker complex CpCo(μ-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)]–with [PtMe3I]4; according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)]– and [PtMe3]+ fragments are ∼64% electrostatic and 36% covalent.

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