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N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure

Vasiliy Georgievich Shtamburg 1
Vasiliy Georgievich Shtamburg
, 
Evgeny A Klots 2
Evgeny A Klots
, 
Mikhail V Gerasimenko 1
Mikhail V Gerasimenko
, 
Oleg Valer'ievich Shishkin 3, 4
Oleg Valer'ievich Shishkin
, 
Roman Igorevich Zubatyuk 3
Roman Igorevich Zubatyuk
, 
Remir Grigorevich Kostyanovsky 5
Remir Grigorevich Kostyanovsky
1 Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine
2 Kirovograd State Pedagogical University, Kirovograd, Ukraine
3 STC 'Institute for Single Crystals', National Academy of Sciences of Ukraine, Kharkov, Ukraine
4 Department of Chemistry, V.N. Karazin Khar'kov National University, Khar'kov, Ukraine
10.1016/j.mencom.2011.11.020
Published 2011-11-10
Communication , Volume 21, Issue 6, 349-350
2
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Shtamburg V. G. et al. N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure // Mendeleev Communications. 2011. Vol. 21. No. 6. pp. 349-350.
GOST all authors (up to 50) Copy
Shtamburg V. G., Klots E. A., Gerasimenko M. V., Shishkin O. V., Zubatyuk R. I., Kostyanovsky R. G. N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure // Mendeleev Communications. 2011. Vol. 21. No. 6. pp. 349-350.
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TY - JOUR
DO - 10.1016/j.mencom.2011.11.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.020
TI - N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure
T2 - Mendeleev Communications
AU - Shtamburg, Vasiliy Georgievich
AU - Klots, Evgeny A
AU - Gerasimenko, Mikhail V
AU - Shishkin, Oleg Valer'ievich
AU - Zubatyuk, Roman Igorevich
AU - Kostyanovsky, Remir Grigorevich
PY - 2011
DA - 2011/11/10
PB - Mendeleev Communications
SP - 349-350
IS - 6
VL - 21
ER -
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@article{2011_Shtamburg,
author = {Vasiliy Georgievich Shtamburg and Evgeny A Klots and Mikhail V Gerasimenko and Oleg Valer'ievich Shishkin and Roman Igorevich Zubatyuk and Remir Grigorevich Kostyanovsky},
title = {N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.020},
number = {6},
pages = {349--350},
doi = {10.1016/j.mencom.2011.11.020}
}
MLA
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Shtamburg, Vasiliy Georgievich, et al. “N,3-Dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide: synthesis and crystal structure.” Mendeleev Communications, vol. 21, no. 6, Nov. 2011, pp. 349-350. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.020.

Abstract

XRD study of crystals of N,3-dimethyl-3-(perhydro-1,3,2-dioxazepin-2-yl)butanamide and N,3-dimethyl-3-(N’,N’-dimethoxyamino)butanamide showed that both of them have similar conformations and similar high degree of nitrogen pyramidality in O–N–O fragment.

References

1.
Shtamburg V.G., Tsygankov A.V., Gerasimenko M.V., Shishkin O.V., Zubatyuk R.I., Mazepa A.V., Kostyanovsky R.G.
Mendeleev Communications, 2011
2.
Asymmetrical nonbridgehead nitrogen-XXVI
Kostyanovsky R.G., Rudchenko V.F., Shtamburg V.G., Chervin I.I., Nasibov S.S.
Tetrahedron, 1981
4.
R. G. Kostyanovsky and V. F. Rudchenko, Dokl. Akad. Nauk SSSR, 1982, 263, 897.[Dokl. Chem. (Engl. Transl.), 1982, 263, 121].
5.
Geminal systems. 17. Acid-catalyzed reactions of N,N-dialkoxyamines
Rudchenko V.F., Shtamburg V.G., Pleshkova A.P., Nasibov S.S., Chervin I.I., Kostyanovskii R.G.
Russian Chemical Bulletin, 1981
6.
2-Alkylperhydro-1,3,2-dioxazepines
Shtamburg V.G., Rudchenko V.F., Chervin I.I., Grinev V.M., Skobelev O.L., Kostyanovskii R.G.
Russian Chemical Bulletin, 1989
7.
V. G. Shtamburg, O.L. Skobelev and L. M. Pritykin, Zh. Org. Khim., 1996, 32, 793.(in Russian).
8.
Perhydro-1,3,6,2-trioxazocine
Rudchenko V.F., Chervin I.I., Kostyanovskii R.G.
Russian Chemical Bulletin, 1992
9.
A. B. Zolotoi, O.A. D’yachenko, I.I. Chervin, V.F. Rudchenko, L.O. Atovmyan and R. G. Kostyanovskii, Khim. Geterotsikl Soedin., 1985, 1341.[Chem. Heterocycl. Compd. (Engl. Transl.), 1985, 21, 1098].
10.
Shtamburg V.G., Tsygankov A.V., Klots E.A., Fedyanin I.V., Lyssenko K.A., Kostyanovsky R.G.
Mendeleev Communications, 2006
11.
Geminal systems
Antipin M.Y., Struchkov Y.T., Rudchenko V.F., Ignatov S.M., Kostyanovskii R.G.
Russian Chemical Bulletin, 1989
13.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007