Abstract
Tungsten(VI) chloride dissolved in the ionic liquids is capable of catalyzing metathesis of 4-octene and co-metathesis of 4-penten-1-ol with ethylene; the latter reaction is preceded by double bond shift in the starting alkenol.
References
1.
Buijsman R.C., van Vuuren E., Sterrenburg J.G.
Organic Letters,
2001
2.
Sémeril D., Olivier-Bourbigou H., Bruneau C., Dixneuf P.H.
Chemical Communications,
2001
3.
Audic N., Clavier H., Mauduit M., Guillemin J.
Journal of the American Chemical Society,
2003
4.
Yao Q., Zhang Y.
Angewandte Chemie - International Edition,
2003
5.
Vasnev A.V., Greish A.A., Kustov L.M.
Mendeleev Communications,
2004
6.
C. Gutler and M. Jautelat, Eur. Patent 1035093, 2000.(Chem. Abstr., 2000, 133, 237853).