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Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit

Cheng-Ling Pan 1
Cheng-Ling Pan
, 
Shao-Ding Sheng 1
Shao-Ding Sheng
, 
Jing Wang 1
Jing Wang
, 
Yu-Song Pan 1
Yu-Song Pan
10.1016/j.mencom.2011.11.008
Published 2011-11-10
Communication , Volume 21, Issue 6, 318-319
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Pan C. et al. Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit // Mendeleev Communications. 2011. Vol. 21. No. 6. pp. 318-319.
GOST all authors (up to 50) Copy
Pan C., Sheng S., Wang J., Pan Y. Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit // Mendeleev Communications. 2011. Vol. 21. No. 6. pp. 318-319.
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TY - JOUR
DO - 10.1016/j.mencom.2011.11.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.008
TI - Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit
T2 - Mendeleev Communications
AU - Pan, Cheng-Ling
AU - Sheng, Shao-Ding
AU - Wang, Jing
AU - Pan, Yu-Song
PY - 2011
DA - 2011/11/10
PB - Mendeleev Communications
SP - 318-319
IS - 6
VL - 21
ER -
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@article{2011_Pan,
author = {Cheng-Ling Pan and Shao-Ding Sheng and Jing Wang and Yu-Song Pan},
title = {Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.008},
number = {6},
pages = {318--319},
doi = {10.1016/j.mencom.2011.11.008}
}
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Pan, Cheng-Ling, et al. “Cleavage and capture of tetrahydrofuran by dysprosium(II) species: a novel tetranuclear Dy2Li2O unit.” Mendeleev Communications, vol. 21, no. 6, Nov. 2011, pp. 318-319. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.11.008.

Keywords

amide
divalent lanthanide
lithium alkoxide,dysprosium

Abstract

The reaction of DyI2 with substituted 2-pyridyl amide [N(SiMe3)(2-C5H3N-6-Me)]– (L) and lithium alkoxide can give a new complex [{(L)2Dy(μ2-OBut)Li}2(μ4-O)] with a Dy2Li2O group, which was characterized by X-ray crystallography.

References

2.
Molecular compounds of “new” divalent lanthanides
Bochkarev M.N.
Coordination Chemistry Reviews, 2004
3.
Recent advances in f element reduction chemistry
Evans W.J.
Journal of Organometallic Chemistry, 2002
4.
Tethered Olefin Studies of Alkene versus Tetraphenylborate Coordination and Lanthanide Olefin Interactions in Metallocenes
Evans W.J., Perotti J.M., Brady J.C., Ziller J.W.
Journal of the American Chemical Society, 2003
5.
Isolation and x-ray crystal structure of the first dinitrogen complex of an f-element metal, [(C5Me5)2Sm]2N2
Evans W.J., Ulibarri T.A., Ziller J.W.
Journal of the American Chemical Society, 1988
6.
Highly Reactive SmII Macrocyclic Clusters: Precursors to N2 Reduction
Ganesan M., Gambarotta S., Yap G.P.
Angewandte Chemie - International Edition, 2001
8.
Facile Dinitrogen Reduction via Organometallic Tm(II) Chemistry
Evans W.J., Allen N.T., Ziller J.W.
Journal of the American Chemical Society, 2001
11.
Multimetallic cooperative activation of N2.
Gambarotta S., Scott J.
Angewandte Chemie - International Edition, 2004
12.
[NdI2(thf)5], the First Crystallographically Authenticated Neodymium(II) Complex
Bochkarev M.N., Fedushkin I.L., Dechert S., Fagin A.A., Schumann H.
Angewandte Chemie - International Edition, 2001
14.
Dinitrogen Reduction and CH Activation by the Divalent Organoneodymium Complex [(C5H2tBu3)2Nd(μ-I)K([18]crown-6)]
Jaroschik F., Momin A., Nief F., Le Goff X., Deacon G., Junk P.
Angewandte Chemie - International Edition, 2009
15.
Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State
Hitchcock P., Lappert M., Maron L., Protchenko A.
Angewandte Chemie - International Edition, 2008
18.
(b) M. L. Cole and P. C. Junk, Chem. Commun., 2005, 2692;
21.
Recent developments in organolanthanide polymerization catalysts
Hou Z., Wakatsuki Y.
Coordination Chemistry Reviews, 2002
22.
Three coordination in metal complexes
Eller P.G., Bradley D.C., Hursthouse M.B., Meek D.W.
Coordination Chemistry Reviews, 1977
24.
Metal—-Metal “Communication” of Rh or Pd with Nd in Novel Heterobinuclear Complexes
Spannenberg A., Oberthür M., Noss H., Tillack A., Arndt P., Kempe R.
Angewandte Chemie - International Edition, 1998
27.
C.-L. Pan, PhD Thesis, The Chinese University of Hong Kong, 2008.
28.
Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran
Mulvey R.E., Blair V.L., Clegg W., Kennedy A.R., Klett J., Russo L.
Nature Chemistry, 2010